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Boiling point (°C) K b (°C⋅kg/mol) Freezing point (°C) K f (°C⋅kg/mol) Data source; ... Acetic Anhydride: 139.0 [6] Ethylene Dichloride: 1.25 83.5 −35 [7 ...
Acetic anhydride, or ethanoic anhydride, is the chemical compound with the formula (CH 3 CO) 2 O. Commonly abbreviated Ac 2 O , it is the simplest isolable anhydride of a carboxylic acid and is widely used as a reagent in organic synthesis .
Triple point: 289.8 K (16.7 °C), ? Pa Critical point: 593 K (320 °C), 57.8 bar Eutectic point with water –26.7 °C Std enthalpy change of fusionΔ fus H o +11.7 kJ/mol Std entropy change of fusionΔ fus S o: 40.5 J/(mol·K) Std enthalpy change of vaporizationΔ vap H o +23.7 kJ/mol Std entropy change of vaporizationΔ vap S o? J/(mol·K ...
Acetic acid can never be truly water-free in an atmosphere that contains water, so the presence of 0.1% water in glacial acetic acid lowers its melting point by 0.2 °C. [ 9 ] A common symbol for acetic acid is AcOH (or HOAc), where Ac is the pseudoelement symbol representing the acetyl group CH 3 −C(=O)− ; the conjugate base , acetate ( CH ...
Chemical formula. C 4 H 7 N O 3: Molar mass: 117.104 g·mol −1 Appearance White powder or needles Melting point: ... of acetic anhydride in glacial (concentrated ...
sec-Butyl acetate, or s-butyl acetate, is an ester commonly used as a solvent in lacquers and enamels, where it is used in the production of acyclic polymers, vinyl resins, and nitrocellulose. [3]
Acetylferrocene is prepared by Friedel-Crafts acylation of ferrocene, usually with acetic anhydride (Ac 2 O): . Fe(C 5 H 5) 2 + Ac 2 O → (C 5 H 5)Fe(C 5 H 4 Ac) + HOAc. The experiment is often conducted in the instructional laboratory to illustrate acylation as well as chromatographic separations.
Acetyl hypochlorite is reported to be produced by the reaction of acetic anhydride and dichlorine monoxide at very low temperatures: [2]. Cl 2 O + (CH3CO) 2 O → 2CH 3 COOCl. The liquid can be distilled at reduced pressure, however it cannot be heated, as it violently decomposes at 100 °C to acetic anhydride, oxygen, and chlorine gas, and reacts with water and alcohols.