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Cisplatin, PtCl 2 (NH 3) 2, is a coordination complex of platinum(II) with two chloride and two ammonia ligands.It is one of the most successful anticancer drugs. A coordination complex is a chemical compound consisting of a central atom or ion, which is usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligands ...
For example, [Ti(H 2 O) 6] 4+ is unknown: the hydrolyzed species [Ti(OH) 2 (H 2 O) n] 2+ is the principal species in dilute solutions. [11] With the higher oxidation states the effective electrical charge on the cation is further reduced by the formation of oxo-complexes.
Chloro(triphenylphosphine)gold(I), which features 2-coordinate metal centre. In chemistry, coordination number, defined originally in 1893 by Alfred Werner, is the total number of neighbors of a central atom in a molecule or ion. [1] [3] The concept is most commonly applied to coordination complexes.
Cyanometallates or cyanometalates are a class of coordination compounds, most often consisting only of cyanide ligands. [1] Most are anions. Cyanide is a highly basic and small ligand, hence it readily saturates the coordination sphere of metal ions.
In crystalline FeSO 4. 7H 2 O, the first coordination sphere of Fe 2+ consists of six water ligands. The second coordination sphere consists of a water of crystallization and sulfate, which interact with the [Fe(H 2 O) 6] 2+ centers. Metal ions can be described as consisting of series of two concentric coordination spheres, the first and second.
In coordination chemistry, a coordinate covalent bond, [1] also known as a dative bond, [2] dipolar bond, [1] or coordinate bond [3] is a kind of two-center, two-electron covalent bond in which the two electrons derive from the same atom. The bonding of metal ions to ligands involves this kind of interaction. [4]
The number of coordination bonds (coordination number) can vary from two in K[Ag(CN) 2] as high as 20 in Th(η 5-C 5 H 5) 4. [ 2 ] One of the most common coordination geometries is octahedral , where six ligands are coordinated to the metal in a symmetrical distribution, leading to the formation of an octahedron if lines were drawn between the ...
Figure 1. An illustration of 1- 2- and 3-dimensionality. A coordination polymer is an inorganic or organometallic polymer structure containing metal cation centers linked by ligands. More formally a coordination polymer is a coordination compound with repeating coordination entities extending in 1, 2, or 3 dimensions. [1] [2]