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For quasi-static and reversible processes, the first law of thermodynamics is: d U = δ Q − δ W {\displaystyle dU=\delta Q-\delta W} where δQ is the heat supplied to the system and δW is the work done by the system.
Thermodynamics is expressed by a mathematical framework of thermodynamic equations which relate various thermodynamic quantities and physical properties measured in a laboratory or production process. Thermodynamics is based on a fundamental set of postulates, that became the laws of thermodynamics.
The solution of the equations is a flow velocity.It is a vector field—to every point in a fluid, at any moment in a time interval, it gives a vector whose direction and magnitude are those of the velocity of the fluid at that point in space and at that moment in time.
Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurements of various thermodynamic properties, but also the application of mathematical methods to the ...
The second vector calculus identity above states that the divergence of the curl of a vector field is zero. Since the (incompressible) mass continuity equation specifies the divergence of flow velocity being zero, we can replace the flow velocity with the curl of some vector ψ so that mass continuity is always satisfied:
Mathematically, mass flux is defined as the limit =, where = = is the mass current (flow of mass m per unit time t) and A is the area through which the mass flows.. For mass flux as a vector j m, the surface integral of it over a surface S, followed by an integral over the time duration t 1 to t 2, gives the total amount of mass flowing through the surface in that time (t 2 − t 1): = ^.
The definition of the Gibbs function is = + where H is the enthalpy defined by: = +. Taking differentials of each definition to find dH and dG, then using the fundamental thermodynamic relation (always true for reversible or irreversible processes): = where S is the entropy, V is volume, (minus sign due to reversibility, in which dU = 0: work other than pressure-volume may be done and is equal ...
In thermodynamics, a component is one of a collection of chemically independent constituents [a] [1] of a system.The number of components represents the minimum number of independent chemical species necessary to define the composition of all phases of the system.