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The latter covers reactions to water, atmospheric gases and biologically produced chemicals with rocks and soils. Water is the principal agent behind both kinds, [1] though atmospheric oxygen and carbon dioxide and the activities of biological organisms are also important. [2] Biological chemical weathering is also called biological weathering. [3]
Hydrolysis (/ h aɪ ˈ d r ɒ l ɪ s ɪ s /; from Ancient Greek hydro- ' water ' and lysis ' to unbind ') is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution , elimination , and solvation reactions in which water is the nucleophile .
A metal ion in aqueous solution or aqua ion is a cation, dissolved in water, of chemical formula [M(H 2 O) n] z+. The solvation number , n , determined by a variety of experimental methods is 4 for Li + and Be 2+ and 6 for most elements in periods 3 and 4 of the periodic table .
These substances break down into dissolved ions as a result. For example, calcium silicate (CaSiO 3), or wollastonite, reacts with carbon dioxide and water to yield a calcium ion, Ca 2+, a bicarbonate ion, HCO 3 −, and dissolved silica. This reaction structure is representative of general silicate weathering of calcium silicate minerals. [9]
Chemical weathering can happen by different mechanisms, depending mainly on the nature of the minerals involved. This includes solution, hydration, hydrolysis, and oxidation weathering. [13] Carbonation weathering is a particular type of solution weathering. [13] Carbonate and silicate minerals are examples of minerals affected by carbonation ...
Chemical weathering of feldspars happens by hydrolysis and produces clay minerals, including illite, smectite, and kaolinite. Hydrolysis of feldspars begins with the feldspar dissolving in water, which happens best in acidic or basic solutions and less well in neutral ones. [30]
When the pH of the solution is increased by adding an alkaline solution to it, the extent of hydrolysis increases. Measurements of pH or colour change are used to derive the equilibrium constant for the reaction. Further hydrolysis may occur, producing dimeric, trimeric or polymeric species containing hydroxy- or oxy- groups.
An idealized equation is shown, in reality the silica produced is hydrated. This hydrolysis reaction is an example of a sol-gel process. The side product is ethanol. The reaction proceeds via a series of condensation reactions that convert the TEOS molecule into a mineral-like solid via the formation of Si-O-Si linkages.