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Fick's first law relates the diffusive flux to the gradient of the concentration. It postulates that the flux goes from regions of high concentration to regions of low concentration, with a magnitude that is proportional to the concentration gradient (spatial derivative), or in simplistic terms the concept that a solute will move from a region of high concentration to a region of low ...
The convection–diffusion equation can be derived in a straightforward way [4] from the continuity equation, which states that the rate of change for a scalar quantity in a differential control volume is given by flow and diffusion into and out of that part of the system along with any generation or consumption inside the control volume: + =, where j is the total flux and R is a net ...
The convection–diffusion equation describes the flow of heat, particles, or other physical quantities in situations where there is both diffusion and convection or advection. For information about the equation, its derivation, and its conceptual importance and consequences, see the main article convection–diffusion equation. This article ...
The diffusion equation is a parabolic partial differential equation. In physics, it describes the macroscopic behavior of many micro-particles in Brownian motion , resulting from the random movements and collisions of the particles (see Fick's laws of diffusion ).
The self-diffusion coefficient of neat water is: 2.299·10 −9 m 2 ·s −1 at 25 °C and 1.261·10 −9 m 2 ·s −1 at 4 °C. [2] Chemical diffusion occurs in a presence of concentration (or chemical potential) gradient and it results in net transport of mass. This is the process described by the diffusion equation.
Dispersion is a process by which (in the case of solid dispersing in a liquid) agglomerated particles are separated from each other, and a new interface between the inner surface of the liquid dispersion medium and the surface of the dispersed particles is generated. This process is facilitated by molecular diffusion and convection. [4]
The higher the diffusivity (of one substance with respect to another), the faster they diffuse into each other. Typically, a compound's diffusion coefficient is ~10,000× as great in air as in water. Carbon dioxide in air has a diffusion coefficient of 16 mm 2 /s, and in water its diffusion coefficient is 0.0016 mm 2 /s. [1] [2]
which represents the ratio of rate of transport by convection to rate of transport by diffusion or dispersion. = characteristic length (m) = effective dispersion coefficient ( m 2 /s) = superficial velocity (m/s) based on empty cross-section. Vessel dispersion number is defined as: