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Hypophosphoric acid can be prepared by the reaction of red phosphorus with sodium chlorite at room temperature. [2]2 P + 2 NaClO 2 + 2 H 2 O → Na 2 H 2 P 2 O 6 + 2 HCl. A mixture of hypophosphoric acid, phosphorous acid (H 3 PO 3) and phosphoric acid (H 3 PO 4) is produced when white phosphorus oxidises in air when partially immersed in water.
For example, pK a for HClO is 7.2, for HClO 2 is 2.0, for HClO 3 is −1 and HClO 4 is a strong acid (pK a ≪ 0). [7] The increased acidity on adding an oxo group is due to stabilization of the conjugate base by delocalization of its negative charge over an additional oxygen atom. [ 47 ]
P 4 + 4 OH − + 4 H 2 O → 4 H 2 PO − 2 + 2 H 2. Any phosphites produced in this step can be selectively precipitated out by treatment with calcium salts. The purified material is then treated with a strong, non-oxidizing acid (often sulfuric acid) to give the free hypophosphorous acid: H 2 PO − 2 + H + → H 3 PO 2. HPA is usually ...
In both cases the phosphoric acid solution usually contains 23–33% P 2 O 5 (32–46% H 3 PO 4). It may be concentrated to produce commercial-or merchant-grade phosphoric acid, which contains about 54–62% P 2 O 5 (75–85% H 3 PO 4). Further removal of water yields superphosphoric acid with a P 2 O 5 concentration above 70% (corresponding to ...
The general formula of a phosphoric acid is H n+2−2x P n O 3n+1−x, where n is the number of phosphorus atoms and x is the number of fundamental cycles in the molecule's structure, between 0 and n + 2 / 2 . Pyrophosphate anion. Trimethyl orthophosphate.
These three equations show that the curves for CO 2 and HCO − 3 intersect at [H +] eq = K 1, and the curves for HCO − 3 and CO 2− 3 intersect at [H +] eq = K 2. Therefore, the values of K 1 and K 2 that were used to create a given Bjerrum plot can easily be found from that plot, by reading off the concentrations at these points of ...
This equation is the equation of a straight line for as a function of pH with a slope of () volt (pH has no units). This equation predicts lower E h {\displaystyle E_{h}} at higher pH values. This is observed for the reduction of O 2 into H 2 O, or OH − , and for reduction of H + into H 2 .
This sum will have a maximum at , representing the point of bond dissociation; summing over all the differences up to this point gives the total energy required to dissociate the molecule, i.e. to promote it from the ground state to an unbound state. This can be written:
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