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The direct fluorination of hydrocarbons with F 2, often diluted with N 2, is useful for highly fluorinated compounds: R 3 CH + F 2 → R 3 CF + HF. Such reactions however are often unselective and require care because hydrocarbons can uncontrollably "burn" in F 2, analogous to the combustion of hydrocarbon in O 2. For this reason, alternative ...
This category has the following 2 subcategories, out of 2 total. P. Perfluoroalkanes (8 P) Perfluoroalkenes (3 P) Pages in category "Fluorocarbons"
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Perfluoroalkanes are very stable because of the strength of the carbon–fluorine bond, one of the strongest in organic chemistry. [4] Its strength is a result of the electronegativity of fluorine imparting partial ionic character through partial charges on the carbon and fluorine atoms, which shorten and strengthen the bond (compared to carbon-hydrogen bonds) through favorable covalent ...
This list is sorted by boiling point of gases in ascending order, but can be sorted on different values. "sub" and "triple" refer to the sublimation point and the triple point, which are given in the case of a substance that sublimes at 1 atm; "dec" refers to decomposition. "~" means approximately.
The United States Environmental Protection Agency (EPA) defines PFAS in the Drinking Water Contaminant Candidate List 5 as substances that contain "at least one of the following three structures: R−CF 2 −CF(R')R", where both the −CF 2 − and −CF− moieties are saturated carbons, and none of the R groups can be hydrogen; R−CF 2 −O ...
For example, R-22 has one carbon atom, one hydrogen atom (2−1 = 1), two fluorine atoms, and one chlorine atom (4−2−1 = 1), so it is chlorodifluoromethane, while R-134 has two carbon atoms (2−1 = 1), two hydrogen atoms (3−1 = 2), four fluorine atoms, and no chlorine atoms (6−2−4 = 0), so it is one of the tetrafluoroethanes. This ...
It also maintains List I of chemicals and List II of chemicals, which contain chemicals that are used to manufacture the controlled substances/illicit drugs. The list is designated within the Controlled Substances Act [ 1 ] but can be modified by the U.S. Attorney General as illegal manufacturing practices change.