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Ionic radius, r ion, is the radius of a monatomic ion in an ionic crystal structure. Although neither atoms nor ions have sharp boundaries, they are treated as if they were hard spheres with radii such that the sum of ionic radii of the cation and anion gives the distance between the ions in a crystal lattice.
For typical ionic solids, the cations are smaller than the anions, and each cation is surrounded by coordinated anions which form a polyhedron.The sum of the ionic radii determines the cation-anion distance, while the cation-anion radius ratio + / (or /) determines the coordination number (C.N.) of the cation, as well as the shape of the coordinated polyhedron of anions.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Ionic strength. The ionic strength of a solution is a measure of the concentration of ions in that solution. Ionic compounds, when dissolved in water, dissociate into ions. The total electrolyte concentration in solution will affect important properties such as the dissociation constant or the solubility of different salts.
In condensed matter physics and inorganic chemistry, the cation-anion radius ratio can be used to predict the crystal structure of an ionic compound based on the relative size of its atoms. It is defined as the ratio of the ionic radius of the positively charged cation to the ionic radius of the negatively charged anion in a cation-anion ...
The following oxidation–reduction tree for a simple ionic compound, AX, where A is a cation and X is an anion, summarizes the various ways in which intrinsic defects can form. Depending on the cation-to-anion ratio, the species can either be reduced and therefore classified as n-type , or if the converse is true, the ionic species is ...
Compounds with a positive ion : The name of the compound is simply the cation's name (usually the same as the element's), followed by the anion. For example, NaCl is sodium chloride, and CaF 2 is calcium fluoride. Cations of transition metals able to take multiple charges are labeled with Roman numerals in parentheses to indicate their charge.
Salt (chemistry) The crystal structure of sodium chloride, NaCl, a typical salt. The purple spheres represent sodium cations, Na +, and the green spheres represent chloride anions, Cl −. The yellow stipples show the electrostatic forces. In chemistry, a salt or ionic compound is a chemical compound consisting of an assembly of positively ...