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In organic chemistry, olefin metathesis is an organic reaction that entails the redistribution of fragments of alkenes (olefins) by the scission and regeneration of carbon-carbon double bonds. [ 1 ] [ 2 ] Because of the relative simplicity of olefin metathesis, it often creates fewer undesired by-products and hazardous wastes than alternative ...
A ray of light being refracted through a glass slab Refraction of a light ray. In optics, the refractive index (or refraction index) of an optical medium is the ratio of the apparent speed of light in the air or vacuum to the speed in the medium.
Below are schematics depicting the thin film measurement process: Thin film characterization involves determining the film's thickness ( t ) plus its refractive index ( n ) and extinction coefficient ( k ) over as wide a wavelength range as possible, preferably covering ultra-violet through near infra-red wavelengths (190–1000 nm).
The metal-mediated processes include a carbonyl-olefination and an olefin–olefin metathesis event. There are two general mechanistic schemes to perform this overall transformation: one, reaction of a [M=CHR 1] reagent with an alkene to generate a new metal alkylidene, which then couples with a carbonyl group to form the desired substituted alkene and an inactive [M=O] species (type A); two ...
In the absence of Doppler shifts, ω does not change on reflection or refraction. Hence, by ( 2 ), the magnitude of the wave vector is proportional to the refractive index. So, for a given ω , if we redefine k as the magnitude of the wave vector in the reference medium (for which n = 1 ), then the wave vector has magnitude n 1 k in the first ...
Refraction at interface. Many materials have a well-characterized refractive index, but these indices often depend strongly upon the frequency of light, causing optical dispersion. Standard refractive index measurements are taken at the "yellow doublet" sodium D line, with a wavelength (λ) of 589 nanometers.
In part correct, [2] being able to successfully explain refraction, reflection, rectilinear propagation and to a lesser extent diffraction, the theory would fall out of favor in the early nineteenth century, as the wave theory of light amassed new experimental evidence. [3] The modern understanding of light is the concept of wave-particle duality.
An enyne metathesis is an organic reaction taking place between an alkyne and an alkene with a metal carbene catalyst forming a butadiene. This reaction is a variation of olefin metathesis. [1] The general scheme is given by scheme 1: When the reaction is intramolecular (in an enyne) it is called ring-closing enyne metathesis or RCEYM (scheme 2):