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Magnetic dipole–dipole interaction, also called dipolar coupling, refers to the direct interaction between two magnetic dipoles. Roughly speaking, the magnetic field of a dipole goes as the inverse cube of the distance, and the force of its magnetic field on another dipole goes as the first derivative of the magnetic field. It follows that ...
It is related to the prototypical Ising model, where at each site of a lattice, a spin {} represents a microscopic magnetic dipole to which the magnetic moment is either up or down. Except the coupling between magnetic dipole moments, there is also a multipolar version of Heisenberg model called the multipolar exchange interaction .
Electric dipole spin resonance (EDSR) is the coupling of the electron spin with an oscillating electric field. Similar to the electron spin resonance (ESR) in which electrons can be excited with an electromagnetic wave with the energy given by the Zeeman effect , in EDSR the resonance can be achieved if the frequency is related to the energy ...
Monopole moments have a 1/r rate of decrease, dipole moments have a 1/r 2 rate, quadrupole moments have a 1/r 3 rate, and so on. The higher the order, the faster the potential drops off. Since the lowest-order term observed in magnetic sources is the dipole term, it dominates at large distances.
For non-protonated carbon atoms the NOE enhancement is small while for carbons that relax by relaxation mechanisms by other than dipole-dipole interactions the NOE enhancement can be significantly reduced. This is one motivation for using deuteriated solvents (e.g. CDCl 3) in 13 C NMR. Since deuterium relaxes by the quadrupolar mechanism, there ...
Energy diagram showing the effects of J-coupling for the molecule hydrogen fluoride. The origin of J-coupling can be visualized by a vector model for a simple molecule such as hydrogen fluoride (HF). In HF, the two nuclei have spin 1 / 2 . Four states are possible, depending on the relative alignment of the H and F nuclear spins with the ...
For a fully oriented molecule, the dipolar coupling for an 1 H-15 N amide group would be over 20 kHz, and a pair of protons separated by 5 Å would have up to ~1 kHz coupling. However the degree of alignment achieved by applying magnetic field is so low that the largest 1 H- 15 N or 1 H- 13 C dipolar couplings are <5 Hz. [ 19 ]
Temperature drift and device mismatches are the major causes of offset errors, and circuits employing direct coupling often integrate offset nulling mechanisms. Some circuits (like power amplifiers) even use coupling capacitors—except that these are present only at the input (and/or output) of the whole system but not between the individual ...