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In contrast, an ammonium ion consists of one nitrogen atom and four hydrogen atoms, with a charge of +1; its chemical formula is N H + 4. Polyatomic ions often are useful in the context of acid–base chemistry and in the formation of salts. Often, a polyatomic ion can be considered as the conjugate acid or base of a neutral molecule.
The phosphotungstate anion, an example of a polyoxometalate. In chemistry, a polyoxometalate (abbreviated POM) is a polyatomic ion, usually an anion, that consists of three or more transition metal oxyanions linked together by shared oxygen atoms to form closed 3-dimensional frameworks.
Ions consisting of only a single atom are termed atomic or monatomic ions, while two or more atoms form molecular ions or polyatomic ions. In the case of physical ionization in a fluid (gas or liquid), "ion pairs" are created by spontaneous molecule collisions, where each generated pair consists of a free electron and a positive ion. [5]
The dichromate ion, Cr 2 O 2− 7, is predominant in more concentrated solutions, except at high pH. The species H 2 CrO 4 and HCr 2 O − 7 are not shown as they are formed only at very low pH. Predominance diagrams can become very complicated when many polymeric species can be formed, [ 10 ] such as in vanadates , molybdates , and tungstates .
The name of the cation (the unmodified element name for monatomic cations) comes first, followed by the name of the anion. [100] [101] For example, MgCl 2 is named magnesium chloride, and Na 2 SO 4 is named sodium sulfate (SO 2− 4, sulfate, is an example of a polyatomic ion).
For ions, the charge on a particular atom may be denoted with a right-hand superscript. For example, Na +, or Cu 2+. The total charge on a charged molecule or a polyatomic ion may also be shown in this way, such as for hydronium, H 3 O +, or sulfate, SO 2− 4. Here + and − are used in place of +1 and −1, respectively.
The metatellurate ion TeO 2− 4 is analogous to the sulfate ion, SO 2− 4 and the selenate ion, SeO 2− 4.Whereas many sulfates and selenates form isomorphous salts [5] the tetrahedral metatellurate ion is only found in a few compounds such as the tetraethylammonium salt (NEt 4) 2 TeO 4. [6]
The barium derivative is useful in the gravimetric analysis of sulfate: if one adds a solution of most barium salts, for instance barium chloride, to a solution containing sulfate ions, barium sulfate will precipitate out of solution as a whitish powder. This is a common laboratory test to determine if sulfate anions are present.
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