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There is an industrial coating process, known as evaporative deposition, whereby a solid material is heated to the gaseous state in a low-pressure chamber, the gas molecules travel across the chamber space and then deposit to the solid state on a target surface, forming a smooth and thin layer on the target surface. Again, the molecules do not ...
In physics, chemistry, and other related fields like biology, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic states of matter : solid , liquid , and gas , and in rare cases, plasma .
At pressures below 5.13 atm and temperatures below −56.4 °C (216.8 K; −69.5 °F) (the triple point), CO 2 changes from a solid to a gas with no intervening liquid form, through a process called sublimation. [a] The opposite process is called deposition, where CO 2 changes from the gas to solid phase (dry ice). At atmospheric pressure ...
The reverse process of sublimation is deposition (also called desublimation), in which a substance passes directly from a gas to a solid phase, without passing through the liquid state. [4] Technically, all solids may sublime, though most sublime at extremely low rates that are hardly detectable under usual conditions.
A similar concept applies to liquid–gas phase changes. [7] Water is an exception which has a solid-liquid boundary with negative slope so that the melting point decreases with pressure. This occurs because ice (solid water) is less dense than liquid water, as shown by the fact that ice floats on water.
However, only solid→liquid and liquid→solid phase changes are practical for PCMs. Although liquid–gas transitions have a higher heat of transformation than solid–liquid transitions, liquid→gas phase changes are impractical for thermal storage because large volumes or high pressures are required to store the materials in their gas ...
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Adsorption is the process by which a gas (or solution) phase molecule (the adsorbate) binds to solid (or liquid) surface atoms (the adsorbent). The reverse of adsorption is desorption, the adsorbate splitting from adsorbent. In a reaction facilitated by heterogeneous catalysis, the catalyst is the adsorbent and the reactants are the adsorbate.