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Enantioselective synthesis, also called asymmetric synthesis, [1] is a form of chemical synthesis.It is defined by IUPAC as "a chemical reaction (or reaction sequence) in which one or more new elements of chirality are formed in a substrate molecule and which produces the stereoisomeric (enantiomeric or diastereomeric) products in unequal amounts."
A metal–air electrochemical cell is an electrochemical cell that uses an anode made from pure metal and an external cathode of ambient air, typically with an aqueous or aprotic electrolyte. [1] [2] During discharging of a metal–air electrochemical cell, a reduction reaction occurs in the ambient air cathode while the metal anode is oxidized.
Electron ionization mass spectrum of toluene. Note parent peak corresponding to molecular mass M = 92 (C 7 H 8 +) and highest peak at M-1 = 91 (C 7 H 7 +, quasi-stable tropylium cation). A mass spectrum is a histogram plot of intensity vs. mass-to-charge ratio (m/z) in a chemical sample, [1] usually acquired using an instrument called a mass ...
This chemical is pyrophoric, bursting into flame in air or in contact with water. It is generally packaged in toluene. It is generally packaged in toluene. [ 3 ]
Toluene is also found in cigarette smoke and car exhaust. If not in contact with air, toluene can remain unchanged in soil or water for a long time. [39] Toluene is a common solvent, e.g. for paints, paint thinners, silicone sealants, [40] many chemical reactants, rubber, printing ink, adhesives (glues), lacquers, leather tanners, and ...
This page provides supplementary chemical data on toluene. MSDS sheets. Structure and properties. Structure and properties Index of refraction, n D: 1.4969 at 20 °C ...
Ethyltoluenes are prepared by alkylation of toluene with ethylene: CH 3 C 6 H 5 + CH 2 =CH 2 → CH 3 C 6 H 4 CH 2 CH 3. These alkylations are catalyzed by various Lewis acids, such as aluminium trichloride. 3- and 4-Ethyltoluenes are mainly of interest as precursors to methylstyrenes: CH 3 C 6 H 4 CH 2 CH 3 → CH 3 C 6 H 4 CH=CH 2 + H 2
There are three common naming conventions for specifying one of the two enantiomers (the absolute configuration) of a given chiral molecule: the R/S system is based on the geometry of the molecule; the (+)- and (−)- system (also written using the obsolete equivalents d- and l-) is based on its optical rotation properties; and the D/L system is based on the molecule's relationship to ...