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Crystal structure of copper(II) bromide. In the solid state CuBr 2 has a polymeric structure, with CuBr 4 planar units connected on opposite sides to form chains. The crystal structure is monoclinic, space group C2/m, with lattice constants a = 714 pm, b = 346 pm, c = 718 pm, e ß = 121° 15'. [7]
In the original paper describing this reaction, methylmagnesium bromide is reacted with isophorone with and without 1 mole percent of added copper(I) chloride (see figure). [10] Without added salt the main products are alcohol B (42%) from nucleophilic addition to the carbonyl group and diene C (48%) as its dehydration reaction product.
The copper(I) ion also oxidizes easily in air. It is commonly prepared by the reduction of cupric salts with sulfite in the presence of bromide. [4] For example, the reduction of copper(II) bromide with sulfite yields copper(I) bromide and hydrogen bromide: 2 CuBr 2 + H 2 O + SO 2− 3 → 2 CuBr + SO 2− 4 + 2 HBr
Crystals of hydrated copper(II) sulfate consist of [Cu(H 2 O) 4] 2+ centers linked to SO 2− 4 ions. Copper is surrounded by six oxygen atoms, provided by two different sulfate groups and four molecules of water. A fifth water resides elsewhere in the framework but does not bind directly to copper. [6]
A sample of copper(I) oxide. Copper forms a rich variety of compounds, usually with oxidation states +1 and +2, which are often called cuprous and cupric, respectively. [1] Copper compounds, whether organic complexes or organometallics, promote or catalyse numerous chemical and biological processes. [2]
Copper bromide can refer to: Copper(I) bromide, CuBr; Copper(II) bromide, CuBr 2 This page was last edited on 31 December 2019, at 11:21 (UTC). Text is ...
Copper(II) chloride is used as a catalyst in a variety of processes that produce chlorine by oxychlorination. The Deacon process takes place at about 400 to 450 °C in the presence of a copper chloride: [8] 4 HCl + O 2 → 2 Cl 2 + 2 H 2 O. Copper(II) chloride catalyzes the chlorination in the production of vinyl chloride and dichloromethane. [8]
The Appel reaction is an organic reaction that converts an alcohol into an alkyl chloride using triphenylphosphine and carbon tetrachloride. [1] The use of carbon tetrabromide or bromine as a halide source will yield alkyl bromides, whereas using carbon tetraiodide, methyl iodide or iodine gives alkyl iodides.