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Trimethyl phosphite is an organophosphorus compound with the formula P(OCH 3) 3, often abbreviated P(OMe) 3.It is a colorless liquid with a highly pungent odor. It is the simplest phosphite ester and finds used as a ligand in organometallic chemistry and as a reagent in organic synthesis.
Phosphite esters are typically prepared by treating phosphorus trichloride with an alcohol. For alkyl alcohols the displaced chloride ion can attack the phosphite, causing dealkylation to give a dialkylphosphite and an organochlorine compound. [1] [2] The overall reaction is as follows: PCl 3 + 3 C 2 H 5 OH → (C 2 H 5 O) 2 P(O)H + 2 HCl + C 2 ...
Chemicals which can be used as weapons, or used in their manufacture, but which have no, or almost no, legitimate applications as well are listed in Schedule 1, whilst Schedule 2 is used for chemicals which have legitimate small-scale applications. The use of Schedule 1, 2, or 3 chemicals as weapons is banned by the Convention.
Trimethyl phosphate is the trimethyl ester of phosphoric acid. It is a colourless, nonvolatile liquid. It is a colourless, nonvolatile liquid. It has some specialized uses in the production of other compounds.
235.308 g·mol −1 Appearance Colorless liquid Odor: Strong fishy odor: Boiling point: 230 °C (446 °F; 503 K) Solubility in water. Slightly soluble in water:
With one equivalent of alcohol and in the absence of base, the first product is alkoxyphosphorodichloridite: [10] PCl 3 + EtOH → PCl 2 (OEt) + HCl. In the absence of base, however, with excess alcohol, phosphorus trichloride converts to diethylphosphite: [11] [12] PCl 3 + 3 EtOH → (EtO) 2 P(O)H + 2 HCl + EtCl. Secondary amines (R 2 NH) form ...
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Dimethyl methylphosphonate can be prepared from trimethyl phosphite and a halomethane (e.g. iodomethane) via the Michaelis–Arbuzov reaction. [2]Dimethyl methylphosphonate is a schedule 2 chemical as it may be used in the production of chemical weapons.