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Silicon tetrabromide, also known as tetrabromosilane, is the inorganic compound with the formula SiBr 4. [1] This colorless liquid has a suffocating odor due to its tendency to hydrolyze with release of hydrogen bromide. [2] The general properties of silicon tetrabromide closely resemble those of the more commonly used silicon tetrachloride. [2]
Silicon tetrabromide Germanium tetrabromide Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Structures of Tetrahalodiboranes. Tetrahalodiboranes are a class of diboron compounds with the formula B 2 X 4 (X = F, Cl, Br, I). These compounds were first discovered in the 1920s, [1] but, after some interest in the middle of the 20th century, were largely ignored in research.
A notable derivative of GeCl 4 is germanium dioxide.In the manufacture of optical fibers, silicon tetrachloride, SiCl 4, and germanium tetrachloride, GeCl 4, are introduced with oxygen into a hollow glass preform, which is carefully heated to allow for oxidation of the reagents to their respective oxides and formation of a glass mixture.
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In a tetrahedral molecular geometry, a central atom is located at the center with four substituents that are located at the corners of a tetrahedron.The bond angles are arccos(− 1 / 3 ) = 109.4712206...° ≈ 109.5° when all four substituents are the same, as in methane (CH 4) [1] [2] as well as its heavier analogues.
Among main group (groups 1, 2, 13–17) alkyl derivatives QR n, where n is the standard bonding number for Q (see lambda convention), the group 14 derivatives QR 4 are notable in being electron-precise: they are neither electron-deficient (having fewer electrons than an octet and tending to be Lewis acidic at Q and usually existing as ...
Phosphorus tribromide, like PCl 3 and PF 3, has both properties of a Lewis base and a Lewis acid. For example, with a Lewis acid such as boron tribromide it forms stable 1 :1 adducts such as Br 3 B · PBr 3. At the same time PBr 3 can react as an electrophile or Lewis acid in many of its reactions, for example with amines.