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This aluminium oxide layer serves as a protective barrier to the underlying unoxidized aluminium and prevents amalgamation from occurring. No reaction takes place when oxidized aluminium is exposed to mercury. However, if any elemental aluminium is exposed (even by a recent scratch), the mercury may combine with it to form the amalgam.
Aluminium can form an amalgam through a reaction with mercury. Aluminium amalgam may be prepared by either grinding aluminium pellets or wire in mercury, or by allowing aluminium wire or foil to react with a solution of mercuric chloride. This amalgam is used as a reagent to reduce compounds, such as the reduction of imines to amines.
Aluminium's electropositive behavior, high affinity for oxygen, and highly negative standard electrode potential are all more similar to those of scandium, yttrium, lanthanum, and actinium, which have ds 2 configurations of three valence electrons outside a noble gas core: aluminium is the most electropositive metal in its group. [1]
Aluminium (or aluminum in North American English) is a chemical element; it has symbol Al and atomic number 13. Aluminium has a density lower than that of other common metals, about one-third that of steel. It has a great affinity towards oxygen, forming a protective layer of oxide on the surface when exposed to air.
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Aluminium triethoxide is produced by treating aluminium with anhydrous alcohol. The aluminium is often activated with iodine or by amalgamation to accelerate the reaction. [6] [2] Aluminium triethoxide has been evaluated as a catalyst for the synthesis of esters and carbonates. [7]
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