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  2. Differential pulse voltammetry - Wikipedia

    en.wikipedia.org/wiki/Differential_pulse_voltammetry

    The system of this measurement is usually the same as that of standard voltammetry.The potential between the working electrode and the reference electrode is changed as a pulse from an initial potential to an interlevel potential and remains at the interlevel potential for about 5 to 100 milliseconds; then it changes to the final potential, which is different from the initial potential.

  3. Cyclic voltammetry - Wikipedia

    en.wikipedia.org/wiki/Cyclic_voltammetry

    In electrochemistry, cyclic voltammetry (CV) is a type of voltammetric measurement where the potential of the working electrode is ramped linearly versus time. Unlike in linear sweep voltammetry , after the set potential is reached in a CV experiment, the working electrode 's potential is ramped in the opposite direction to return to the ...

  4. Voltammetry - Wikipedia

    en.wikipedia.org/wiki/Voltammetry

    In 1942, the English electrochemist Archie Hickling (University of Leicester) built the first three electrodes potentiostat, which was an advancement for the field of electrochemistry. [26] He used this potentiostat to control the voltage of an electrode.

  5. Randles–Sevcik equation - Wikipedia

    en.wikipedia.org/wiki/Randles–Sevcik_equation

    In electrochemistry, the Randles–ŠevĨík equation describes the effect of scan rate on the peak current (i p) for a cyclic voltammetry experiment. For simple redox events where the reaction is electrochemically reversible, and the products and reactants are both soluble, such as the ferrocene/ferrocenium couple, i p depends not only on the concentration and diffusional properties of the ...

  6. Linear sweep voltammetry - Wikipedia

    en.wikipedia.org/wiki/Linear_sweep_voltammetry

    Since the production of methane from CO 2 is an irreversible reaction, cyclic voltammetry did not present any distinct advantage over linear sweep voltammetry. This group found that the biocathode produced higher current densities than a plain carbon cathode and that methane can be produced from a direct electric current without the need of ...

  7. Reference electrode - Wikipedia

    en.wikipedia.org/wiki/Reference_electrode

    A pseudo reference electrode is a term that is not well defined and borders on having multiple meanings since pseudo and quasi are often used interchangeably. They are a class of electrodes named pseudo-reference electrodes because they do not maintain a constant potential but vary predictably with conditions.

  8. Electroanalytical methods - Wikipedia

    en.wikipedia.org/wiki/Electroanalytical_methods

    In practice, the analyte solution is usually disposed of since it is difficult to separate the analyte from the bulk electrolyte, and the experiment requires a small amount of analyte. A normal experiment may involve 1–10 mL solution with an analyte concentration between 1 and 10 mmol/L.

  9. Electrosynthesis - Wikipedia

    en.wikipedia.org/wiki/Electrosynthesis

    It has been reported that formate can be formed by the electrochemical reduction of CO 2 (in the form of bicarbonate) at a lead cathode at pH 8.6: [24] HCO − 3 + H 2 O + 2e − → HCO − 2 + 2OH −. or CO 2 + H 2 O + 2e − → HCO − 2 + OH −. If the feed is CO 2 and oxygen is evolved at the anode, the total reaction is: CO 2 + OH − ...

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