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For a cleaner product, the reaction is conducted in the gas phase or in an organic solvent. Ethylene fluorohydrin is obtained differently, by boiling hydrogen fluoride with a 5–6% solution of ethylene oxide in diethyl ether. The ether normally has a water content of 1.5–2%; in absence of water, ethylene oxide polymerizes. [37]
Friedel–Crafts alkylations can be reversible. Although this is usually undesirable it can be exploited; for instance by facilitating transalkylation reactions. [10] 1,3-Diisopropylbenzene is produced via transalkylation, a special form of Friedel–Crafts alkylation. It also allows alkyl chains to be added reversibly as protecting groups.
James Crafts, the son of Royal Altamont Crafts and Marianne Mason (daughter of Senator Jeremiah Mason), [3] [4] was born in Boston, Massachusetts and graduated from Harvard University in 1858. Although he never received his Ph.D. , he studied chemistry in Germany at the Academy of Mines (1859) of Freiberg , and served as an assistant to Robert ...
Friedel–Crafts reaction, a type of organic reaction developed by Charles Friedel and James Crafts in 1877. Friedel's law, named after Georges Friedel, the crystallographer, is a property of Fourier transforms of real functions. Friedel's salt, discovered by Georges Friedel, is an anion exchanger mineral belonging to the family of the layered ...
To start, a diluted cleaning solution (white vinegar, bleach and detergent) is sprayed onto all surfaces to be cleaned, Using the same machine, the area is then rinsed; this is typically followed by vacuum suctioning that removes the applied liquid along with the suspended solids and dissolved contaminants that have been removed from the surface.
Friedel's wife's father was the engineer, Charles Combes. [4] The Friedel family is a rich lineage of French scientists: Georges Friedel (1865–1933), French crystallographer and mineralogist; son of Charles; Edmond Friedel (1895–1972), French Polytechnician and mining engineer, founder of BRGM, the French geological survey; son of Georges