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  2. Redox - Wikipedia

    en.wikipedia.org/wiki/Redox

    Redox (/ ˈrɛdɒks / RED-oks, / ˈriːdɒks / REE-doks, reduction–oxidation[2] or oxidation–reduction[3]: 150 ) is a type of chemical reaction in which the oxidation states of the reactants change. [4] Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the ...

  3. Reduction potential - Wikipedia

    en.wikipedia.org/wiki/Reduction_potential

    In aqueous solutions, redox potential is a measure of the tendency of the solution to either gain or lose electrons in a reaction. A solution with a higher (more positive) reduction potential than some other molecule will have a tendency to gain electrons from this molecule (i.e. to be reduced by oxidizing this other molecule) and a solution with a lower (more negative) reduction potential ...

  4. Latimer diagram - Wikipedia

    en.wikipedia.org/wiki/Latimer_diagram

    In a Latimer diagram, because by convention redox reactions are shown in the direction of reduction (gain of electrons), the most highly oxidized form of the element is on the left side, with successively lower oxidation states to the right side. The species are connected by arrows, and the numerical value of the standard potential (in volts ...

  5. Redox gradient - Wikipedia

    en.wikipedia.org/wiki/Redox_gradient

    A redox gradient is a series of reduction-oxidation (redox) reactions sorted according to redox potential. [4][5] The redox ladder displays the order in which redox reactions occur based on the free energy gained from redox pairs. [4][5][6] These redox gradients form both spatially and temporally as a result of differences in microbial ...

  6. Cyclic voltammetry - Wikipedia

    en.wikipedia.org/wiki/Cyclic_voltammetry

    Cyclic voltammetry (CV) has become an important and widely used electroanalytical technique in many areas of chemistry. It is often used to study a variety of redox processes, to determine the stability of reaction products, the presence of intermediates in redox reactions, [10] electron transfer kinetics, [11] and the reversibility of a ...

  7. Nernst equation - Wikipedia

    en.wikipedia.org/wiki/Nernst_equation

    Nernst equation. In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction (half-cell or full cell reaction) from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities (often ...

  8. Standard hydrogen electrode - Wikipedia

    en.wikipedia.org/wiki/Standard_hydrogen_electrode

    The hydrogen electrode is based on the redox half cell corresponding to the reduction of two hydrated protons, 2H+(aq), into one gaseous hydrogen molecule, H2 (g). General equation for a reduction reaction: The reaction quotient (Qr) of the half-reaction is the ratio between the chemical activities (a) of the reduced form (the reductant, ared ...

  9. Marcus theory - Wikipedia

    en.wikipedia.org/wiki/Marcus_theory

    Redox occurs with Gibbs free reaction energy =. From the reaction rate's temperature dependence an activation energy is determined, and this activation energy is interpreted as the energy of the transition state in a reaction diagram. The latter is drawn, according to Arrhenius and Eyring, as an energy diagram with the reaction coordinate as ...