Search results
Results From The WOW.Com Content Network
Xanthate salts of alkali metals are produced by the treatment of an alcohol, alkali, and carbon disulfide.The process is called xanthation. [2] In chemical terminology, the alkali reacts with the alcohol to produce an alkoxide, which is the nucleophile that adds to the electrophilic carbon atom in CS 2. [3]
The intermediate is a xanthate. It is named for its discoverer, the Russian chemist Lev Aleksandrovich Chugaev (1873–1922), who first reported the reaction sequence in 1899. In the first step, a xanthate salt is formed out of the alkoxide and carbon disulfide (CS 2). With the addition of iodomethane, the alkoxide is transformed into a methyl ...
Sodium ethyl xanthate (SEX) [3] is an organosulfur compound with the chemical formula CH 3 CH 2 OCS 2 Na. It is a pale yellow powder, which is usually obtained as the dihydrate. Sodium ethyl xanthate is used in the mining industry as a flotation agent. [4] A closely related potassium ethyl xanthate (KEX) is obtained as the anhydrous salt.
Process tracing methods in psychology are defined as observations which are made before the participant has come to a decision. These observations are used to present us with information regarding the psychological processes occurring within a participant, while they are weighing their choices. [ 1 ]
In terms of mechanism, an ideal RAFT polymerization has several features. The pre-equilibrium and re-initiation steps are completed very early in the polymerization meaning that the major product of the reaction (the RAFT polymer chains, RAFT-P n), all start growing at approximately the same time. The forward and reverse reactions of the main ...
Ethyl xanthic acid is obtained by the action of dilute sulfuric acid on potassium ethyl xanthate at 0 °C. [4] Ethyl xanthic acid is a colorless, labile oil. In aqueous solution, it decomposes rapidly by a unimolecular pathway to give carbon disulfide and ethanol. [1] [4] [5]
Potassium amyl xanthate (/pəˈtæsiəm ˌæmɪl ˈzænθeɪt/) is an organosulfur compound with the chemical formula CH 3 (CH 2) 4 OCS 2 K. It is a pale yellow powder with a pungent odor that is soluble in water. It is widely used in the mining industry for the separation of ores using the flotation process.
Other thiocarbonyl reagents can replace the thioacyl chloride. In one variation the reagent is the imidazole 1,1'-thiocarbonyldiimidazole (TCDI), for example in the total synthesis of pallescensin B. [5] TCDI is especially good to primary alcohols because there is no resonance stabilization of the xanthate; the nitrogen lonepair is involved in the aromatic sextet.