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In thermodynamics, the Joule–Thomson effect (also known as the Joule–Kelvin effect or Kelvin–Joule effect) describes the temperature change of a real gas or liquid (as differentiated from an ideal gas) when it is expanding; typically caused by the pressure loss from flow through a valve or porous plug while keeping it insulated so that no heat is exchanged with the environment.
The energy required to accelerate a 1 kg mass at 1 m/s 2 through a distance of 1 m. The kinetic energy of a 2 kg mass travelling at 1 m/s, or a 1 kg mass travelling at 1.41 m/s. The energy required to lift an apple up 1 m, assuming the apple has a mass of 101.97 g. The heat required to raise the temperature of 0.239 g of water from 0 °C to 1 ...
Thomson collaborated with Joule, mainly by correspondence, Joule conducting experiments, Thomson analysing the results and suggesting further experiments. The collaboration lasted from 1852 to 1856. Its published results did much to bring about general acceptance of Joule's work and the kinetic theory.
Real gases are non-ideal gases whose molecules occupy space and have interactions; consequently, they do not adhere to the ideal gas law. To understand the behaviour of real gases, the following must be taken into account: compressibility effects; variable specific heat capacity; van der Waals forces; non-equilibrium thermodynamic effects;
When the potential energy is positive, a constant energy expansion reduces potential energy and increases kinetic energy, resulting in an increase in temperature. This behavior has only been observed for hydrogen and helium; which have very weak attractive interactions. For other gases this "Joule inversion temperature" appears to be extremely ...
So for >, an expansion at constant enthalpy increases temperature as the work done by the repulsive interactions of the gas is dominant, and so the change in kinetic energy is positive. But for T < T inv {\displaystyle T<T_{\text{inv}}} , expansion causes temperature to decrease because the work of attractive intermolecular forces dominates ...
Joule's apparatus for measuring the mechanical equivalent of heat. Most established scientists, such as William Henry, [13] as well as Thomas Thomson, believed that there was enough uncertainty in the caloric theory to allow its adaptation to account for the new results. It had certainly proved robust and adaptable up to that time.
The Joule–Thomson effect, the temperature change of a gas when it is forced through a valve or porous plug while keeping it insulated so that no heat is exchanged with the environment. The Gough–Joule effect or the Gow–Joule effect, which is the tendency of elastomers to contract if heated while they are under tension.