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Methane clathrate (CH 4 ·5.75H 2 O) or (4CH 4 ·23H 2 O), also called methane hydrate, hydromethane, methane ice, fire ice, natural gas hydrate, or gas hydrate, is a solid clathrate compound (more specifically, a clathrate hydrate) in which a large amount of methane is trapped within a crystal structure of water, forming a solid similar to ice.
In organic chemistry, a hydrate is a compound formed by the hydration, i.e. "Addition of water or of the elements of water (i.e. H and OH) to a molecular entity". [5] For example: ethanol , CH 3 −CH 2 −OH , is the product of the hydration reaction of ethene , CH 2 =CH 2 , formed by the addition of H to one C and OH to the other C, and so ...
Methane clathrate block embedded in the sediment of hydrate ridge, off Oregon, USA. Clathrate hydrates, or gas hydrates, clathrates, or hydrates, are crystalline water-based solids physically resembling ice, in which small non-polar molecules (typically gases) or polar molecules with large hydrophobic moieties are trapped inside "cages" of hydrogen bonded, frozen water molecules.
Clathrate cavities. For example, 5 12 (dodecahedral) and 5 12 6 2 (tetrakaidecahedral) make up a Type I (sI) structure. [4] Clathrates can be divided into two categories: clathrate hydrates and inorganic clathrates. Each clathrate is made up of a framework and guests that reside the framework.
If methane is detected (by using a spectrometer for example) this may indicate that life is, or recently was, present. This was debated [ 25 ] when methane was discovered in the Martian atmosphere by M.J. Mumma of NASA's Goddard Flight Center, and verified by the Mars Express Orbiter (2004) [ 26 ] and in Titan 's atmosphere by the Huygens probe ...
The free gas zone is a zone of freed methane in a hydrate formation, beneath the hydrate stability zone. It can influence the rate of methane output at a ridge or ridge region. A large free gas zone makes more methane available to be released into the open ocean, and, thus, can likely be more influential on climate change than a smaller one. [11]
Uncharged compounds such as methane can also be solvated by water and also have a hydration number. Although solvation shells can contain inner and outer shell solvent-solute interactions, the hydration number generally focuses on the inner shell solvent molecules that directly interact with the solute.
Biological methanation takes place in a separate methanation plant. The gas is completely converted into methane before the infeed into the gas grid. The carbon dioxide, produced in a gas processing system, is converted into methane in a separate methanation plant, by adding hydrogen and can then be fed into the gas grid.