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Fluorination of enolizable ketones gives a mixture of the difluoroalkane and vinyl fluoride. In glyme with fuming sulfuric acid , the vinyl fluoride product predominates. [ 11 ] Electron-rich carbonyl compounds, such as esters and amides, do not react with DAST or other aminosulfuranes.
Dimethoxyethane is also a good solvent for oligo- and polysaccharides. Sodium naphthalide dissolved in dimethoxyethane is used as a PTFE etching solution that removes fluorine atoms from the surface, which get replaced by oxygen, hydrogen, and water. This physically etches the surface as well to prepare the surface for better adhesion.
Metallic solids are held together by a high density of shared, delocalized electrons, resulting in metallic bonding. Classic examples are metals such as copper and aluminum , but some materials are metals in an electronic sense but have negligible metallic bonding in a mechanical or thermodynamic sense (see intermediate forms ).
Glyme may refer to: Any of the glycol ethers, a class of solvents, usually dimethoxyethane if not otherwise specified; River Glyme, a river in Oxfordshire, England
Substitution reactions in organic chemistry are classified either as electrophilic or nucleophilic depending upon the reagent involved, whether a reactive intermediate involved in the reaction is a carbocation, a carbanion or a free radical, and whether the substrate is aliphatic or aromatic. Detailed understanding of a reaction type helps to ...
Complexes are held together by weaker electrostatic forces which are omni-directional and thus the ligands alone dictate the symmetry and coordination of complexes. Steric factors therefore dominate, with coordinative saturation of the metal being balanced against inter-ligand repulsion.
A binder or binding agent is any material or substance that holds or draws other materials together to form a cohesive whole mechanically, chemically, by adhesion or cohesion. More narrowly, binders are liquid or dough-like substances that harden by a chemical or physical process and bind fibres, filler powder and other particles added into it.
Solvents can be broadly classified into two categories: polar and non-polar. A special case is elemental mercury, whose solutions are known as amalgams; also, other metal solutions exist which are liquid at room temperature. Generally, the dielectric constant of the solvent provides a rough measure of a solvent's polarity.