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Liquid oxygen has a clear cyan color and is strongly paramagnetic: it can be suspended between the poles of a powerful horseshoe magnet. [2] Liquid oxygen has a density of 1.141 kg/L (1.141 g/ml), slightly denser than liquid water, and is cryogenic with a freezing point of 54.36 K (−218.79 °C; −361.82 °F) and a boiling point of 90.19 K (−182.96 °C; −297.33 °F) at 1 bar (14.5 psi).
Molecular oxygen is a good example. Even in the frozen solid it contains di-radical molecules resulting in paramagnetic behavior. The unpaired spins reside in orbitals derived from oxygen p wave functions, but the overlap is limited to the one neighbor in the O 2 molecules. The distances to other oxygen atoms in the lattice remain too large to ...
Diamagnetic materials, like water, or water-based materials, have a relative magnetic permeability that is less than or equal to 1, and therefore a magnetic susceptibility less than or equal to 0, since susceptibility is defined as χ v = μ v − 1. This means that diamagnetic materials are repelled by magnetic fields.
Magnetic susceptibility indicates whether a material is attracted into or repelled out of a magnetic field. Paramagnetic materials align with the applied field and are attracted to regions of greater magnetic field. Diamagnetic materials are anti-aligned and are pushed away, toward regions of lower magnetic fields.
Liquid oxygen is so magnetic that, in laboratory demonstrations, a bridge of liquid oxygen may be supported against its own weight between the poles of a powerful magnet. [37] [c] Singlet oxygen is a name given to several higher-energy species of molecular O 2 in which all the electron spins are paired.
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This means that the effects are additive, and a table of "diamagnetic contributions", or Pascal's constants, can be put together. [6] [7] [8] With paramagnetic compounds the observed susceptibility can be adjusted by adding to it the so-called diamagnetic correction, which is the diamagnetic susceptibility calculated with the values from the ...
The ortho and para forms of water have recently been isolated. Para water was found to be 25% more reactive for a proton-transfer reaction. [29] [30] Molecular oxygen (O 2) also exists in three lower-energy triplet states and one singlet state, as ground-state paramagnetic triplet oxygen and energized highly reactive diamagnetic singlet oxygen.