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Arsenate readily reacts with metals to form arsenate metal compounds. [2] [3] Arsenate is a moderate oxidizer and an electron acceptor, with an electrode potential of +0.56 V for its reduction to arsenite. [4] Due to arsenic having the same valency and similar atomic radius to phosphorus, arsenate shares similar geometry and reactivity with ...
Arsenic trioxide powder.. Compounds of arsenic resemble in some respects those of phosphorus which occupies the same group (column) of the periodic table.The most common oxidation states for arsenic are: −3 in the arsenides, which are alloy-like intermetallic compounds, +3 in the arsenites, and +5 in the arsenates and most organoarsenic compounds.
The other sodium arsenates are NaH 2 AsO 4 and Na 3 AsO 4, the latter being called sodium arsenate. Disodium hydrogen arsenate is highly toxic. The salt is the conjugate base of arsenic acid. It is a white, water-soluble solid. [1] Being a diprotic acid, its acid-base properties is described by two equilibria: H 2 AsO − 4 + H 2 O ⇌ HAsO 2−
The solubility product was determined to be 10 −18.06 for aluminium arsenate hydrate of formula AlAsO 4 ·3.5H 2 O. [1] Like gallium arsenate and boron arsenate, it adopts the α-quartz-type structure. The high pressure form has a rutile-type structure in which aluminium and arsenic are six-coordinate.
Arsenic(V) acid is a weak acid and its salts, known as arsenates, [36] are a major source of arsenic contamination of groundwater in regions with high levels of naturally-occurring arsenic minerals. [37] Synthetic arsenates include Scheele's Green (cupric hydrogen arsenate, acidic copper arsenate), calcium arsenate, and lead hydrogen arsenate.
The monomethylated acid, methanearsonic acid (CH 3 AsO(OH) 2), is a precursor to fungicides (tradename Neoasozin) in the cultivation of rice and cotton. Derivatives of phenylarsonic acid (C 6 H 5 AsO(OH) 2 ) are used as feed additives for livestock, including 4-hydroxy-3-nitrobenzenearsonic acid (3-NHPAA or Roxarsone), ureidophenylarsonic acid ...
Arsenate minerals usually refer to the naturally occurring orthoarsenates, possessing the (AsO 4) 3− anion group and, more rarely, other arsenates with anions like AsO 3 (OH) 2− (also written HAsO 4 2−) (example: pharmacolite Ca(AsO 3 OH). 2H 2 O) or (very rarely) [AsO 2 (OH) 2] − (example: andyrobertsite). Arsenite minerals are much ...
An arsenate arsenite is a chemical compound or salt that contains arsenate and arsenite anions (AsO 3 3-and AsO 4 3-). These are mixed anion compounds or mixed valence compounds. Some have third anions. Most known substances are minerals, but a few artificial arsenate arsenite compounds have been made. Many of the minerals are in the Hematolite ...