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For a similar process at constant temperature and volume, the change in Helmholtz free energy must be negative, <. Thus, a negative value of the change in free energy (G or A) is a necessary condition for a process to be spontaneous. This is the most useful form of the second law of thermodynamics in chemistry, where free-energy changes can be ...
In regular cold matter, quarks, fundamental particles of nuclear matter, are confined by the strong force into hadrons that consist of 2–4 quarks, such as protons and neutrons. Quark matter or quantum chromodynamical (QCD) matter is a group of phases where the strong force is overcome and quarks are deconfined and free to move.
When matter is transferred into a system, the internal energy and potential energy associated with it are transferred into the new combined system. ( u Δ M ) i n = Δ U s y s t e m {\displaystyle \left(u\,\Delta M\right)_{\rm {in}}=\Delta U_{\rm {system}}} where u denotes the internal energy per unit mass of the transferred matter, as measured ...
The definition of the Gibbs function is = + where H is the enthalpy defined by: = +. Taking differentials of each definition to find dH and dG, then using the fundamental thermodynamic relation (always true for reversible or irreversible processes): = where S is the entropy, V is volume, (minus sign due to reversibility, in which dU = 0: work other than pressure-volume may be done and is equal ...
The various solid/liquid/gas transitions are classified as first-order transitions because they involve a discontinuous change in density, which is the (inverse of the) first derivative of the free energy with respect to pressure. Second-order phase transitions are continuous in the first derivative (the order parameter, which is the first ...
No matter what, Lee Crain, the lawyer for some of the plaintiffs hurt in Lafayette Park, said Trump could end up answering questions under oath for the lawsuit while he is president.
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