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Cations are plotted in milliequivalents per liter on the left side of the zero axis, one to each horizontal axis, and anions are plotted on the right side. Stiff patterns are useful in making a rapid visual comparison between water from different sources. An alternative to the Stiff diagram is the Maucha diagram.
The diamond is a matrix transformation of a graph of the anions (sulfate + chloride/ total anions) and cations (sodium + potassium/total cations). [ 4 ] The Piper diagram is suitable for comparing the ionic composition of a set of water samples, but does not lend itself to spatial comparisons.
In inorganic chemistry, Fajans' rules, formulated by Kazimierz Fajans in 1923, [1] [2] [3] are used to predict whether a chemical bond will be covalent or ionic, and depend on the charge on the cation and the relative sizes of the cation and anion. They can be summarized in the following table:
Cations are positively (+) charged ions while anions are negatively (−) charged. This can be remembered with the help of the following mnemonics. Cats have paws ⇔ Cations are pawsitive. [27] Ca+ion: The letter t in cation looks like a + (plus) sign. [28] An anion is a negative ion. (An egative ion ⇒ Anion). [29]
For typical ionic solids, the cations are smaller than the anions, and each cation is surrounded by coordinated anions which form a polyhedron.The sum of the ionic radii determines the cation-anion distance, while the cation-anion radius ratio + / (or /) determines the coordination number (C.N.) of the cation, as well as the shape of the coordinated polyhedron of anions.
The 2nd group of anions consist of Cl −, Br −, I −, NO − 3 and C 2 O 2− 4. The group reagent for Group 2 anion is concentrated sulfuric acid (H 2 SO 4). After addition of the acid, chlorides, bromides and iodides will form precipitates with silver nitrate. The precipitates are white, pale yellow, and yellow, respectively.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
In table salt (NaCl, also known as sodium chloride) the sodium ion (positively charged) is the counterion for the chloride ion (negatively charged) and vice versa. A counterion will be more commonly referred to as an anion or a cation, depending on whether it is negatively or positively charged. Thus, the counterion to an anion will be a cation ...