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For example, sulfuric acid (H 2 SO 4) is a diprotic acid. Since only 0.5 mol of H 2 SO 4 are needed to neutralize 1 mol of OH −, the equivalence factor is: f eq (H 2 SO 4) = 0.5. If the concentration of a sulfuric acid solution is c(H 2 SO 4) = 1 mol/L, then its normality is 2 N. It can also be called a "2 normal" solution.
It is used in chemistry to keep track of the changes in amount of substance of the reactants and also organize a set of conditions that one wants to solve with. [1] Some sources refer to a RICE table (or box or chart) where the added R stands for the reaction to which the table refers. [ 2 ]
The solution has 1 mole or 1 equiv Na +, 1 mole or 2 equiv Ca 2+, and 3 mole or 3 equiv Cl −. An earlier definition, used especially for chemical elements , holds that an equivalent is the amount of a substance that will react with 1 g (0.035 oz) of hydrogen , 8 g (0.28 oz) of oxygen , or 35.5 g (1.25 oz) of chlorine —or that will displace ...
This suggests a shortcut which works for any number of reagents. Just calculate this formula for each reagent, and the reagent that has the lowest value of this formula is the limiting reagent. We can apply this shortcut in the above example.
Figure 2 gives an example; in this example, the two x-intercepts differ by about 0.2 mL but this is a small discrepancy, given the large equivalence volume (0.5% error). Similar equations can be written for the titration of a weak base by strong acid (Gran, 1952; Harris, 1998).
In analytical chemistry, a solution of any substance which contains one equivalent per litre is known as a normal solution (abbreviated N), so the example sodium hydroxide solution would be 0.0893 N. [3] [13] The relative uncertainty (u r) in the measured concentration can be estimated by assuming a Gaussian distribution of the measurement ...