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The other sodium arsenates are NaH 2 AsO 4 and Na 3 AsO 4, the latter being called sodium arsenate. Disodium hydrogen arsenate is highly toxic. The salt is the conjugate base of arsenic acid. It is a white, water-soluble solid. [1] Being a diprotic acid, its acid-base properties is described by two equilibria: H 2 AsO − 4 + H 2 O ⇌ HAsO 2−
Sodium arsenate is the inorganic compound with the formula Na 3 AsO 4. Related salts are also called sodium arsenate, including Na 2 HAsO 4 (disodium hydrogen arsenate) and NaH 2 AsO 4 (sodium dihydrogen arsenate). The trisodium salt is a white or colourless solid that is highly toxic. It is usually handled as the dodecahydrate Na 3 AsO 4. 12H ...
Related salts are also called sodium arsenate, including Na 2 HAsO 4 (disodium hydrogen arsenate) and NaH 2 AsO 4 (sodium dihydrogen arsenate). Sodium dihydrogen arsenate is a colorless solid that is highly toxic. The salt is the conjugate base of arsenic acid: H 3 AsO 4 ⇌ H 2 AsO − 4 + H + (K 1 = 10 −2.19) In the laboratory, it is ...
This reaction generates glucose-6-arsenate and 6-arsenogluconate, which act as analogs for glucose-6-phosphate and 6-phosphogluconate. [40] At the substrate level, during glycolysis , glucose-6-arsenate binds as a substrate to glucose-6-phosphate dehydrogenase, and also inhibits hexokinase through negative feedback. [ 40 ]
These reactions take place even at room temperature, and result in a discolouration of the original chemical. [3] Sodium dihydrogen arsinide NaAsH 2 reacts with alkyl halides RX (where X = F, Cl, Br, I, and R is alkyl) to make dialkylarsine AsHR 2. Potassium dihydrogen arsinide KAsH 2 reacts with alkyl halides to make trialkylarsine AsR 3. [4]
Samarium(III) arsenate can be produced by reacting sodium arsenate (Na 3 AsO 4) and samarium(III) chloride (SmCl 3) in solution: [4] Na 3 AsO 4 + SmCl 3 → 3 NaCl + SmAsO 4 ↓ References
Arsenate readily reacts with metals to form arsenate metal compounds. [2] [3] Arsenate is a moderate oxidizer and an electron acceptor, with an electrode potential of +0.56 V for its reduction to arsenite. [4] Due to arsenic having the same valency and similar atomic radius to phosphorus, arsenate shares similar geometry and reactivity with ...
In its standard state arsine is a colorless, denser-than-air gas that is slightly soluble in water (2% at 20 °C) [1] and in many organic solvents as well. [citation needed] Arsine itself is odorless, [5] but it oxidizes in air and this creates a slight garlic or fish-like scent when the compound is present above 0.5 ppm. [6]