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The electrolyte in the electrolytic plating cell should contain positive ions (cations) of the metal to be deposited. These cations are reduced at the cathode to the metal in the zero valence state. For example, the electrolyte for copper electroplating can be a solution of copper(II) sulfate , which dissociates into Cu 2+ cations and SO 2−
The plating of zinc was developed at the beginning of the 20th century. At that time, the electrolytic solution was cyanide-based. A significant innovation occurred in the 1960s with the introduction of the first acid chloride-based electrolyte. [2] The 1980s saw a return to alkaline electrolytes, only this time, without the use of cyanide.
Before plating, the surface of the material must be thoroughly cleaned. Unwanted solids left on the surface cause poor plating. Cleaning is usually achieved by a series of chemical baths, including non-polar solvents to remove oils and greases, as well as acids and alkalis to remove oxides, insoluble organics, and other surface contaminants.
Electroless deposition is an important process in the electronic industry for metallization of substrates. Other metallization of substrates also include physical vapor deposition (PVD), chemical vapor deposition (CVD), and electroplating which produce thin metal films but require high temperature, vacuum, and a power source respectively. [20]
Plating is a finishing process in which a metal is deposited on a surface. Plating has been done for hundreds of years; it is also critical for modern technology. Plating is used to decorate objects, for corrosion inhibition, to improve solderability, to harden, to improve wearability, to reduce friction, to improve paint adhesion, to alter conductivity, to improve IR reflectivity, for ...
Copper plating on aluminium. Copper electroplating is the process of electroplating a layer of copper onto the surface of a metal object. Copper is used both as a standalone coating and as an undercoat onto which other metals are subsequently plated. [1]
Electrowinning is the oldest industrial electrolytic process. The English chemist Humphry Davy obtained sodium metal in elemental form for the first time in 1807 by the electrolysis of molten sodium hydroxide. Electrorefining of copper was first demonstrated experimentally by Maximilian, Duke of Leuchtenberg in 1847. [2]
anodizing – electrolytic passivation process used to increase the thickness of the natural oxide layer, producing a porous surface which can accept organic or inorganic dyes easily. In the case of titanium, niobium, and stainless steel, the colour formed is dependent on the thickness of the oxide (which is determined by the anodizing voltage).