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In laboratories, a slurry of dry ice in an organic solvent is a useful freezing mixture for cold chemical reactions and for condensing solvents in rotary evaporators. [38] Dry ice and acetone forms a cold bath of −78 °C (−108 °F; 195 K), which can be used for instance to prevent thermal runaway in a Swern oxidation .
Comparison of phase diagrams of carbon dioxide (red) and water (blue) showing the carbon dioxide sublimation point (middle-left) at 1 atmosphere. As dry ice is heated, it crosses this point along the bold horizontal line from the solid phase directly into the gaseous phase. Water, on the other hand, passes through a liquid phase at 1 atmosphere.
Dry ice: Tetrachloroethylene-22 Dry ice: Carbon Tetrachloride-23 Dry ice: 1,3-Dichlorobenzene-25 Dry ice: o-Xylene-29 Liquid N 2: Bromobenzene-30 Dry ice: m-Toluidine-32 Dry ice: 3-Heptanone-38 Ice: Calcium chloride hexahydrate -40 1 to 0.8 ratio of salt to ice. Dry ice: Acetonitrile-41 Dry ice: Pyridine-42 Dry ice: Cyclohexanone-46 Dry ice: m ...
A cooling bath or ice bath, in laboratory chemistry practice, is a liquid mixture which is used to maintain low temperatures, typically between 13 °C and −196 °C. These low temperatures are used to collect liquids after distillation , to remove solvents using a rotary evaporator , or to perform a chemical reaction below room temperature ...
This Wikipedia page provides a comprehensive list of boiling and freezing points for various solvents.
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Another type of binary phase diagram is a boiling-point diagram for a mixture of two components, i. e. chemical compounds. For two particular volatile components at a certain pressure such as atmospheric pressure, a boiling-point diagram shows what vapor (gas) compositions are in equilibrium with given liquid compositions depending on ...
At the phase transition point for a substance, for instance the boiling point, the two phases involved - liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the boiling point the gaseous form is the more stable.