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Boric acid is a weak acid, with pK a (the pH at which buffering is strongest because the free acid and borate ion are in equal concentrations) of 9.24 in pure water at 25 °C. But apparent p K a is substantially lower in swimming pool or ocean waters because of interactions with various other molecules in solution.
Its reaction with hydrochloric acid to form boric acid is: Na 2 B 4 O 7 ·10H 2 O + 2 HCl → 4 H 3 BO 3 + 2 NaCl + 5 H 2 O. Borax is sufficiently stable to find use as a primary standard for acid-base titrimetry. [17]: p.316 Molten borax dissolves many metal oxides to form glasses.
This page provides supplementary chemical data on boric acid. Thermodynamic properties. Phase behavior Triple point? K (? °C), ? Pa Critical point? K (? °C), ?
Commonly used mineral acids are sulfuric acid (H 2 SO 4), hydrochloric acid (HCl) and nitric acid (HNO 3); these are also known as bench acids. [1] Mineral acids range from superacids (such as perchloric acid) to very weak ones (such as boric acid). Mineral acids tend to be very soluble in water and insoluble in organic solvents.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Boric acid will initially decompose into steam, (H 2 O (g)) and metaboric acid (HBO 2) at around 170 °C, and further heating above 300 °C will produce more steam and diboron trioxide. The reactions are: H 3 BO 3 → HBO 2 + H 2 O 2 HBO 2 → B 2 O 3 + H 2 O. Boric acid goes to anhydrous microcrystalline B 2 O 3 in a heated fluidized bed. [21 ...
Some of the borates above may have more than one isomeric or crystalline form. Some may decompose when dissolved in water. Note that the anion of the "anhydrous borax" is different from that of its "hydrates". Some of the anhydrous borates above can be crystallized from molten mixtured of sodium oxide and boric oxide. [6]
Boron trifluoride reacts with water to give boric acid and fluoroboric acid. The reaction commences with the formation of the aquo adduct, H 2 O−BF 3, which then loses HF that gives fluoroboric acid with boron trifluoride. [22] 4 BF 3 + 3 H 2 O → 3 H[BF 4] + B(OH) 3