Search results
Results From The WOW.Com Content Network
In the NO − 3 anion, the oxidation state of the central nitrogen atom is V (+5). This corresponds to the highest possible oxidation number of nitrogen. Nitrate is a potentially powerful oxidizer as evidenced by its explosive behaviour at high temperature when it is detonated in ammonium nitrate (NH 4 NO 3), or black powder, ignited by the shock wave of a primary explosive.
Nitrous acid is also highly unstable, tending to disproportionate: 3 HNO 2 (aq) ⇌ H 3 O + + NO − 3 + 2 NO. This reaction is slow at 0 °C. [2] Addition of acid to a solution of a nitrite in the presence of a reducing agent, such as iron(II), is a way to make nitric oxide (NO) in the laboratory.
The difference between the resulting molecular structures of nitro compounds and nitrates (NO − 3) is that the nitrogen atom in nitro compounds is directly bonded to a non-oxygen atom (typically carbon or another nitrogen atom), whereas in nitrate esters (also called organic nitrates), the nitrogen is bonded to an oxygen atom that in turn ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
A common nitrate test, known as the brown ring test [2] can be performed by adding iron(II) sulfate to a solution of a nitrate, then slowly adding concentrated sulfuric acid such that the acid forms a layer below the aqueous solution. A brown ring will form at the junction of the two layers, indicating the presence of the nitrate ion. [3]
In these areas, nitrate (NO 3 −) or nitrite (NO 2 − ) can be used as a substitute terminal electron acceptor instead of oxygen (O 2 ), a more energetically favourable electron acceptor. Terminal electron acceptor is a compound that gets reduced in the reaction by receiving electrons.
In addition, the nitrate radical (NO 3) is formed by the reaction between NO 2 and ozone. At night, NO 3 further reacts with NO 2 and establishes an equilibrium reaction with dinitrogen pentoxide (N 2 O 5). [35] Via heterogeneous reaction, N 2 O 5 reacts with water vapor or liquid water and forms nitric acid (HNO 3).
This solution has a boiling temperature of 120.5 °C (249 °F) at 1 atm. It is known as "concentrated nitric acid". The azeotrope of nitric acid and water is a colourless liquid at room temperature. Two solid hydrates are known: the monohydrate HNO 3 ·H 2 O or oxonium nitrate [H 3 O] + [NO 3] − and the trihydrate HNO 3 ·3H 2 O.