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Polyatomic ions often are useful in the context of acid–base chemistry and in the formation of salts. Often, a polyatomic ion can be considered as the conjugate acid or base of a neutral molecule. For example, the conjugate base of sulfuric acid (H 2 SO 4) is the polyatomic hydrogen sulfate anion (HSO − 4).
The cation is always named first. Ions can be metals, non-metals or polyatomic ions. Therefore, the name of the metal or positive polyatomic ion is followed by the name of the non-metal or negative polyatomic ion. The positive ion retains its element name whereas for a single non-metal anion the ending is changed to -ide.
Ions consisting of only a single atom are termed atomic or monatomic ions, while two or more atoms form molecular ions or polyatomic ions. In the case of physical ionization in a fluid (gas or liquid), "ion pairs" are created by spontaneous molecule collisions, where each generated pair consists of a free electron and a positive ion. [5]
An atom (or ion) whose oxidation number increases in a redox reaction is said to be oxidized (and is called a reducing agent). It is accomplished by loss of one or more electrons. The atom whose oxidation number decreases gains (receives) one or more electrons and is said to be reduced. This relation can be remembered by the following mnemonics.
This is sometimes the case when multiple atoms of the same type surround the central atom, and is especially common for polyatomic ions. When this situation occurs, the molecule's Lewis structure is said to be a resonance structure, and the molecule exists as a resonance hybrid. Each of the different possibilities is superimposed on the others ...
2 ion is formed with bond order 1/2. Another molecule that is precluded based on this principle is diberyllium. Beryllium has an electron configuration 1s 2 2s 2, so there are again two electrons in the valence level. However, the 2s can mix with the 2p orbitals in diberyllium, whereas there are no p orbitals in the valence level of hydrogen or ...
Each polyatomic ion in a compound is written individually in order to illustrate the separate groupings. For example, the compound dichlorine hexoxide has an empirical formula ClO 3, and molecular formula Cl 2 O 6, but in liquid or solid forms, this compound is more correctly shown by an ionic condensed formula [ClO 2] + [ClO 4] −, which ...
In chemistry, the pentazenium cation (also known as pentanitrogen) is a positively-charged polyatomic ion with the chemical formula N + 5 and structure N−N−N−N−N.Together with solid nitrogen polymers and the azide anion, it is one of only three poly-nitrogen species obtained in bulk quantities.