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Phosphonium ion Structure of PH + 4, the parent phosphonium cation. In chemistry, the term phosphonium (more obscurely: phosphinium) describes polyatomic cations with the chemical formula PR + 4 (where R is a hydrogen or an alkyl, aryl, organyl or halogen group). These cations have tetrahedral structures.
A phosphonium ylide can be prepared rather straightforwardly. Typically, triphenylphosphine is allowed to react with an alkyl halide in a mechanism analogous to that of an S N 2 reaction. This quaternization forms an alkyltriphenylphosphonium salt, which can be isolated or treated in situ with a strong base (in this case, butyllithium) to form ...
Meaning: "good", "well"; also extended via Neo-Latin to mean "true". Used in a variety of ways, often to indicate well-preserved specimens, well-developed bones, "truer" examples of fossil forms, or simply admiration on the part of the discoverer.
In contrast to phosphonium ylides used in the Wittig reaction, phosphonate-stabilized carbanions are more nucleophilic but less basic. Likewise, phosphonate-stabilized carbanions can be alkylated. Unlike phosphonium ylides, the dialkylphosphate salt byproduct is easily removed by aqueous extraction. Several reviews have been published.
The reaction proceeds smoothly when the R group is aliphatic. When all of A, B and R are aryl groups, a stable phosphonium salt is formed and the reaction proceeds no further under normal conditions. Heating to higher temperatures in the presence of alcohols has been known to give the isomerization product.
Graphic representation of carbon, hydrogen, nitrogen, oxygen, phosphorus, and sulfur. CHNOPS and CHON are mnemonic acronyms for the most common elements in living organisms. . "CHON" stands for carbon, hydrogen, oxygen, and nitrogen, which together make up more than 95 percent of the mass of biological system
Phosphonates feature tetrahedral phosphorus centers. They are structurally closely related to (and often prepared from) phosphorous acid. [3]Phosphonic acids and derivatives are chemically and structurally related to phosphorous acid.
A large fraction of the chemical elements that occur naturally on the Earth's surface are essential to the structure and metabolism of living things. Four of these elements (hydrogen, carbon, nitrogen, and oxygen) are essential to every living thing and collectively make up 99% of the mass of protoplasm. [1]