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A method to produce 3,3-dimethylpentane is to react tert-amyl chloride (CH 3 CH 2 (CH 3)C 2 Cl) with propionaldehyde producing 3,3-dimethylpentan-2-ol. This is then dehydrated to produce 3,3-dimethylpent-2-ene, which when hydrogenated produces some 3,3-dimethylpentane, but also 2,3-dimethylpentane. [2]
The boiling point of 89.7 °C is 0.3 °C higher than the value of 89.4 °C predicted by Wiener's formula, based on the structure of the molecule and the boiling point of n-heptane. [2] [3] The speed of sound at 3 MHz is 1149.5 m/s at 20 °C and 889.5 m/s at 80 °C. [7] [8] [9]
2,2-Dimethylpentane can form a clathrate hydrate with helper gas molecules. The type of clathrate formed is called "clathrate H". 2,2-Dimethylpentane was the first compound for which the structure was determined. The clathrate has 34 molecules of water per molecule, and also has xenon and hydrogen sulfide as helper molecules.
1,2,3,4,5-Pentakis(4-butylphenyl)-1,3-cyclopentadiene is an organochemical compound from the diene group and a cyclopentadiene derivative. The anion of this compound is used as a sterically demanding ligand, often abbreviated as Cp [BIG] , in the organometallic chemistry of sandwich compounds .
The branched isomers are 2-methylbut-1-ene, 3-methylbut-1-ene (isopentene), and 2-methylbut-2-ene (isoamylene). Isoamylene is one of the three main byproducts of deep catalytic cracking (DCC), which is very similar to the operation of fluid catalytic cracking (FCC).
It can be prepared by base-catalyzed isomerization of 2,3-dimethyl-1-butene. [2] Another route involves direct dimerization of propylene. [3] It can also be produced by photolysis of tetramethylcyclobutane-1,3-dione. [4]
The Claisen rearrangement is a powerful carbon–carbon bond-forming chemical reaction discovered by Rainer Ludwig Claisen. [1] The heating of an allyl vinyl ether will initiate a [3,3]-sigmatropic rearrangement to give a γ,δ-unsaturated carbonyl, driven by exergonically favored carbonyl CO bond formation with Δ(Δ f H) ca. −25 kcal/mol (−100 kJ/mol).
[2] Axial to tetrahedral chirality transfer in the Nazarov cyclization of allenyl vinyl ketones. Tius has additionally developed a camphor-based auxiliary for achiral allenes that was employed in the first asymmetric synthesis of roseophilin. The key step employs an unusual mixture of hexafluoro-2-propanol and trifluoroethanol as solvent. [2] [20]