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Ammonium iron(II) sulfate, or Mohr's salt, is the inorganic compound with the formula (NH 4) 2 SO 4 ·Fe(SO 4)·6H 2 O. Containing two different cations, Fe 2+ and NH + 4, it is classified as a double salt of ferrous sulfate and ammonium sulfate. It is a common laboratory reagent because it is readily crystallized, and crystals resist oxidation ...
Ammonium iron(III) sulfate, NH 4 Fe(SO 4) 2 ·12 H 2 O, or NH 4 [Fe(H 2 O) 6](SO 4) 2 ·6 H 2 O, also known as ferric ammonium sulfate (FAS) or iron alum, is a double salt in the class of alums, which consists of compounds with the general formula AB(SO 4) 2 · 12 H 2 O. [2] It has the appearance of weakly violet, octahedrical crystals.
Mohr's salt, ammonium iron(II) sulfate, [NH 4] 2 [Fe(H 2 O) 6](SO 4) 2.. A double salt is a salt that contains two or more different cations or anions.Examples of double salts include alums (with the general formula M I M III (SO 4) 2 ·12H 2 O) and Tutton's salts (with the general formula (M I) 2 M II (SO 4) 2 ·6H 2 O). [1]
Ammonia – NH 3 [33]; Ammonium azide – [NH 4]N 3 [34]; Ammonium bicarbonate – [NH 4]HCO 3 [35]; Ammonium bisulfate – [NH 4]HSO 4 [36]; Ammonium bromide – NH 4 Br [37]; Ammonium chromate – [NH 4] 2 CrO 4 [38]
4 ions. For example, addition of barium chloride, precipitates out barium sulfate. The filtrate on evaporation yields ammonium chloride. Ammonium sulfate forms many double salts (ammonium metal sulfates) when its solution is mixed with equimolar solutions of metal sulfates and the solution is slowly evaporated.
The name of the cation (the unmodified element name for monatomic cations) comes first, followed by the name of the anion. [100] [101] For example, MgCl 2 is named magnesium chloride, and Na 2 SO 4 is named sodium sulfate (SO 2− 4, sulfate, is an example of a polyatomic ion).
An example that illustrates the problem is shown in Baes & Mesmer, p. 119. [1] A trimeric species must be formed from a chemical reaction of a dimer with a monomer, with the implication that the value of the stability constant of the dimer must be "known", having been determined using separate experimental data.
Other examples include the vanadous Tutton salt (NH 4) 2 V(SO 4) 2 (H 2 O) 6 and the chromous Tutton salt (NH 4) 2 Cr(SO 4) 2 (H 2 O) 6. [5] In solids and solutions, the M' 2+ ion exists as a metal aquo complex [M'(H 2 O) 6] 2+. Related to the Tutton's salts are the alums, which are also double salts but with the formula MM'(SO 4) 2 (H 2 O) 12 ...