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A delayed coker is a type of coker whose process consists of heating a residual oil feed to its thermal cracking temperature in a furnace with multiple parallel passes. This cracks the heavy, long chain hydrocarbon molecules of the residual oil into coker gas oil and petroleum coke .
De-coking: The cracking reaction forms petroleum coke as a byproduct. In coil visbreaking, this deposits in the tubes of the furnace and will eventually lead to fouling or blocking of the tubes. The same will occur in the drum of a soaker visbreaker, though the lower temperatures used in the soaker drum lead to fouling at a much slower rate.
Thermal cracking is currently used to "upgrade" very heavy fractions or to produce light fractions or distillates, burner fuel and/or petroleum coke. Two extremes of the thermal cracking in terms of the product range are represented by the high-temperature process called "steam cracking" or pyrolysis (ca. 750 °C to 900 °C or higher) which ...
The first thermal cracking method, the Shukhov cracking process, was invented by Vladimir Shukhov (Patent of Russian Empire No. 12926 on November 27, 1891). While the Russians contended that the Burton process was essentially a slight modification of the Shukhov process, Americans refused to concede and the Burton-Humphreys patent remained in use.
This petroleum coke can either be fuel grade (high in sulphur and metals) or anode grade (low in sulphur and metals). The raw coke from the coker is often referred to as green coke. [1] In this context, "green" means unprocessed. The further processing of green coke by calcining in a rotary kiln removes residual volatile hydrocarbons from the coke.
Needle coke, also called acicular coke, is a highly crystalline petroleum coke used in the production of electrodes for the steel and aluminium industries and is particularly valuable because the electrodes must be replaced regularly. Needle coke is produced exclusively from either fluid catalytic cracking (FCC) decant oil or coal tar pitch.
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Shukhov designed and built the first thermal cracking device for the petrochemical industry.His patent (Shukhov cracking process – patent of Russian empire No. 12926 from November 27, 1891) on cracking was used to invalidate Standard Oil's patents (Burton process – Patent of United States No. 1,049,667 on January 7, 1913) on oil refineries.