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An isothermal process is a type of thermodynamic process in which the temperature T of a system remains constant: ΔT = 0. This typically occurs when a system is in contact with an outside thermal reservoir, and a change in the system occurs slowly enough to allow the system to be continuously adjusted to the temperature of the reservoir through heat exchange (see quasi-equilibrium).
The dependence of work on the path of the thermodynamic process is also unrelated to reversibility, since expansion work, which can be visualized on a pressure–volume diagram as the area beneath the equilibrium curve, is different for different reversible expansion processes (e.g. adiabatic, then isothermal; vs. isothermal, then adiabatic ...
The Carnot cycle is a cycle composed of the totally reversible processes of isentropic compression and expansion and isothermal heat addition and rejection. The thermal efficiency of a Carnot cycle depends only on the absolute temperatures of the two reservoirs in which heat transfer takes place, and for a power cycle is:
A Carnot cycle is an ideal thermodynamic cycle proposed by French physicist Sadi Carnot in 1824 and expanded upon by others in the 1830s and 1840s. By Carnot's theorem, it provides an upper limit on the efficiency of any classical thermodynamic engine during the conversion of heat into work, or conversely, the efficiency of a refrigeration system in creating a temperature difference through ...
Reversible isothermal expansion of the gas at the "hot" temperature, T H (isothermal heat addition or absorption). During this step (A to B) the gas is allowed to expand and it does work on the surroundings. The temperature of the gas (the system) does not change during the process, and thus the expansion is isothermic.
The expansion space is heated externally, and the gas undergoes near-isothermal expansion. 270° to 0°, near-constant-volume (or near-isometric or isochoric) heat removal. The gas is passed through the regenerator, thus cooling the gas, and transferring heat to the regenerator for use in the next cycle. 0° to 90°, pseudo-isothermal compression.
For reversible processes, an isentropic transformation is carried out by thermally "insulating" the system from its surroundings. Temperature is the thermodynamic conjugate variable to entropy, thus the conjugate process would be an isothermal process , in which the system is thermally "connected" to a constant-temperature heat bath.
The Carnot cycle, which has a quantum equivalent, [11] is reversible so the four processes that comprise it, two isothermal and two isentropic, can also be reversed. When a Carnot cycle runs in reverse, it is called a reverse Carnot cycle. A refrigerator or heat pump that acts according to the reversed Carnot cycle is called a Carnot ...