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Humic substances account for 50 – 90% of cation exchange capacity in soils. "Humic substances" is an umbrella term covering humic acid, fulvic acid and humin, which differ in solubility. By definition, humic acid (HA) is soluble in water at neutral and alkaline pH, but insoluble at acidic pH < 2. Fulvic acid (FA) is soluble in water at any pH.
Potassium humate is used in agriculture as a fertilizer additive to increase the efficiency of fertilizers especially nitrogen- and phosphorus-based fertilizer inputs. Other salts of humic acid are manufactured, mainly sodium humate, which is used in animal health supplements. It also can be used in aquaculture.
Potentially, arsenic adsorption could occur as a humic-acid-metal-As bridging ligand, or possibly adsorbed to the clay that is bound to the humic acid itself as well. [15] Lead, on the other hand, has been shown to increase binding to humic substances with increasing pH and decreasing ionic strength.
It is used to condition soils either by applying it directly to the land, or by providing a source of humic acid or potassium humate for application. The carbon geosequestration potential of Leonardite, particularly to rapidly accelerate microbial action to lock up and retain carbon in soils, provides the basis for extensive research in Victoria on the organic fertilising aspect of brown coal.
The organic components can be subdivided into fractions that are soluble, largely humic acids, and insoluble, the humins. Humins make up about 50% of the organic matter in soil. Humins make up about 50% of the organic matter in soil.
Increasing the soil's pH increases the ability of naturally occurring humic substances to improve infiltration in hydrophobic soils. Humic acid is only water-soluble at a pH greater than 6.5, while fulvic acid is soluble at all pH ranges. Both resident acids have a property that enables them to reduce the surface tension of water when in solution.
Processed organic fertilizers include compost, liquid plant manures, humic acid, grain meal, amino acids, and seaweed extracts. Other examples are natural enzyme-digested proteins. Decomposing crop residue (green manure) from prior years is another source of fertility.
Fulvic acid is the genus that contains the matter that has the lowest molecular weight, is soluble in acids and alkalis, and is susceptible to microbial action. Humic acid is the genus that contains the intermediate matter that has medial molecular weight, is soluble in alkalis and insoluble in acids, and has some resistance to microbial action.