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3 Spectral data. 4 Structure and ... This page provides supplementary chemical data on Lithium chloride. Solubility. Solubility of LiCl in various solvents
Lithium chloride is a chemical compound with the formula Li Cl.The salt is a typical ionic compound (with certain covalent characteristics), although the small size of the Li + ion gives rise to properties not seen for other alkali metal chlorides, such as extraordinary solubility in polar solvents (83.05 g/100 mL of water at 20 °C) and its hygroscopic properties.
In 1860, the unexpected appearance of sky-blue and dark red was observed in spectral emissions by Robert Bunsen and Gustav Kirchhoff, leading to the discovery of two alkali metals, caesium and rubidium (dark red). [4] [1] Today, this low-cost method is used in secondary education to teach students to detect metals in samples qualitatively. [2]
Spectral lines of lithium: ... These estimates are "based principally on old data, ... Lithium chloride and lithium bromide are hygroscopic and are used as ...
The FT-IR spectra were recorded using a Nicolet 170SX or a JASCO FT/IR-410 spectrometer. For spectra recorded in the Nicolet spectrometer, the data were stored at intervals of 0.5 cm −1 in the 4,000 – 2,000 cm −1 region and of 0.25 cm −1 in the 2,000 – 400 cm −1 region and the spectral resolution was 0.25 cm −1.
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This is particularly relevant when measurements are made on concentrated salt solutions. For example, a solvation number of 3 for a lithium chloride solution could be interpreted as being due to the equilibrium [Li(H 2 O) 4] + + Cl − ⇌ [Li(H 2 O) 3 Cl] + H 2 O. lying wholly in favour of the ion pair.
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