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Iron(II) carbonate, or ferrous carbonate, is a chemical compound with formula FeCO 3 , that occurs naturally as the mineral siderite . At ordinary ambient temperatures, it is a green-brown ionic solid consisting of iron(II) cations Fe 2+
Siderite is a mineral composed of iron(II) carbonate (FeCO 3).Its name comes from the Ancient Greek word σίδηρος (sídēros), meaning "iron".A valuable iron ore, it consists of 48% iron and lacks sulfur and phosphorus.
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A carbonate is a salt of carbonic acid, (H 2 CO 3), [2] characterized by the presence of the carbonate ion, a polyatomic ion with the formula CO 2− 3. The word "carbonate" may also refer to a carbonate ester , an organic compound containing the carbonate group O=C(−O−) 2 .
Green rust is a generic name for various green crystalline chemical compounds containing iron(II) and iron(III) cations, the hydroxide (OH −) anion, and another anion such as carbonate (CO 2− 3), chloride (Cl −), or sulfate (SO 2− 4), in a layered double hydroxide (LDH) structure. The most studied varieties are the following: [1]
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Bowen also predicts that other natural options may become more popular, including minerals such as calcium carbonate (white) and iron oxides (red, brown and black), fruit and vegetable extracts ...
When the iron-bearing groundwater came into contact with more oxygen-rich groundwater, the reduced iron was converted back to insoluble iron oxide, which formed the concretions. [74] [75] [76] It is possible that reduced iron first formed siderite concretions that were subsequently oxidized. Iron-oxidizing bacteria may have played a role. [77]