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Pourbaix diagram of iron. [1] The Y axis corresponds to voltage potential. In electrochemistry, and more generally in solution chemistry, a Pourbaix diagram, also known as a potential/pH diagram, E H –pH diagram or a pE/pH diagram, is a plot of possible thermodynamically stable phases (i.e., at chemical equilibrium) of an aqueous electrochemical system.
The simplest definition for a potential gradient F in one dimension is the following: [1] = = where ϕ(x) is some type of scalar potential and x is displacement (not distance) in the x direction, the subscripts label two different positions x 1, x 2, and potentials at those points, ϕ 1 = ϕ(x 1), ϕ 2 = ϕ(x 2).
If the force is not conservative, then defining a scalar potential is not possible, because taking different paths would lead to conflicting potential differences between the start and end points. Gravitational force is an example of a conservative force, while frictional force is an example of a non-conservative force.
This function represents half of the rate of energy dissipation of the system through friction. The force of friction is negative the velocity gradient of the dissipation function, F → f = − ∇ v R ( v ) {\displaystyle {\vec {F}}_{f}=-\nabla _{v}R(v)} , analogous to a force being equal to the negative position gradient of a potential.
By example, in physics, the electric field is the negative vector gradient of the electric potential. The directional derivative of a scalar function f(x) of the space vector x in the direction of the unit vector u (represented in this case as a column vector) is defined using the gradient as follows.
The electric field of the dipole is the negative gradient of the potential, leading to: [7] = (^) ^. Thus, although two closely spaced opposite charges are not quite an ideal electric dipole (because their potential at short distances is not that of a dipole), at distances much larger than their separation, their dipole moment p appears ...
When it is operating in the second or fourth quadrant, current is forced to flow through the device from the negative to the positive voltage terminal, against the opposing force of the electric field, so the electric charges are gaining potential energy. Thus the device is converting some other form of energy into electric energy.
The same approach implies that the negative of the Laplacian of the gravitational potential is the mass distribution. Often the charge (or mass) distribution are given, and the associated potential is unknown. Finding the potential function subject to suitable boundary conditions is equivalent to solving Poisson's equation.