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Boltzmann constant: The Boltzmann constant, k, is one of seven fixed constants defining the International System of Units, the SI, with k = 1.380 649 x 10 −23 J K −1. The Boltzmann constant is a proportionality constant between the quantities temperature (with unit kelvin) and energy (with unit joule).
The Stefan–Boltzmann constant, σ, is derived from other known physical constants: = where k is the Boltzmann constant, the h is the Planck constant, and c is the speed of light in vacuum. [19] [4]: 388
kT (also written as k B T) is the product of the Boltzmann constant, k (or k B), and the temperature, T.This product is used in physics as a scale factor for energy values in molecular-scale systems (sometimes it is used as a unit of energy), as the rates and frequencies of many processes and phenomena depend not on their energy alone, but on the ratio of that energy and kT, that is, on E ...
The extra constant factor introduced in the denominator was introduced because, unlike the discrete form, the continuous form shown above is not dimensionless. As stated in the previous section, to make it into a dimensionless quantity, we must divide it by h 3N (where h is usually taken to be the Planck constant).
For example, it predicts that every atom in a monatomic ideal gas has an average kinetic energy of 3 / 2 k B T in thermal equilibrium, where k B is the Boltzmann constant and T is the (thermodynamic) temperature. More generally, equipartition can be applied to any classical system in thermal equilibrium, no matter how complicated.
The proportionality constant k B is one of the fundamental constants of physics and is named the Boltzmann constant in honor of its discoverer. Boltzmann's entropy describes the system when all the accessible microstates are equally likely. It is the configuration corresponding to the maximum of entropy at equilibrium.
In 1900 Max Planck empirically obtained an expression for black-body radiation expressed in terms of wavelength λ = c/ν (Planck's law): =, where h is the Planck constant, and k B is the Boltzmann constant. Planck's law does not suffer from an ultraviolet catastrophe and agrees well with the experimental data, but its full significance (which ...
Boltzmann's equation = is the realization that the entropy is proportional to with the constant of proportionality being the Boltzmann constant. Using the ideal gas equation of state ( PV = NkT ), It follows immediately that β = 1 / k T {\displaystyle \beta =1/kT} and α = − μ / k T {\displaystyle \alpha =-\mu /kT} so that the ...