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PV work is often measured in units of litre-atmospheres where 1 L·atm = 101.325 J. However, the litre-atmosphere is not a recognized unit in the SI system of units, which measures P in pascals (Pa), V in m 3, and PV in joules (J), where 1 J = 1 Pa·m 3. PV work is an important topic in chemical thermodynamics.
This is the definition declared in the modern International System of Units in 1960. [13] The definition of the joule as J = kg⋅m 2 ⋅s −2 has remained unchanged since 1946, but the joule as a derived unit has inherited changes in the definitions of the second (in 1960 and 1967), the metre (in 1983) and the kilogram . [14]
The erg is a unit of energy equal to 10 −7 joules (100 nJ). It is not an SI unit, instead originating from the centimetre–gram–second system of units (CGS). Its name is derived from ergon (ἔργον), a Greek word meaning 'work' or 'task'. [1] An erg is the amount of work done by a force of one dyne exerted for a distance of one centimetre.
Energy is defined via work, so the SI unit of energy is the same as the unit of work – the joule (J), named in honour of James Prescott Joule [1] and his experiments on the mechanical equivalent of heat. In slightly more fundamental terms, 1 joule is equal to 1 newton metre and, in terms of SI base units
The work function depends on the configurations of atoms at the surface of the material. For example, on polycrystalline silver the work function is 4.26 eV, but on silver crystals it varies for different crystal faces as (100) face: 4.64 eV, (110) face: 4.52 eV, (111) face: 4.74 eV. [13] Ranges for typical surfaces are shown in the table below ...
Hartree defined units based on three physical constants: [1]: 91 Both in order to eliminate various universal constants from the equations and also to avoid high powers of 10 in numerical work, it is convenient to express quantities in terms of units, which may be called 'atomic units', defined as follows:
Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...
Usage of N⋅m is discouraged by the SI authority, since it can lead to confusion as to whether the quantity expressed in newton-metres is a torque measurement, or a measurement of work. [15] Another unit for work is the foot-pound, which comes from the English system of measurement. As the unit name suggests, it is the product of pounds for ...