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Nitrogen fixation is a chemical process by which molecular dinitrogen (N 2) is converted into ammonia (NH 3). [1] It occurs both biologically and abiologically in chemical industries. Biological nitrogen fixation or diazotrophy is catalyzed by enzymes called nitrogenases. [2]
Most biological nitrogen fixation occurs by the activity of molybdenum (Mo)-nitrogenase, found in a wide variety of bacteria and some Archaea. Mo-nitrogenase is a complex two-component enzyme that has multiple metal-containing prosthetic groups. [22] An example of free-living bacteria is Azotobacter.
Abiological nitrogen fixation describes chemical processes that fix (react with) N 2, usually with the goal of generating ammonia. The dominant technology for abiological nitrogen fixation is the Haber process, which uses iron-based heterogeneous catalysts and H 2 to convert N 2 to NH 3. This article focuses on homogeneous (soluble) catalysts ...
Nitrogenase is an enzyme responsible for catalyzing nitrogen fixation, which is the reduction of nitrogen (N 2) to ammonia (NH 3) and a process vital to sustaining life on Earth. [9] There are three types of nitrogenase found in various nitrogen-fixing bacteria: molybdenum (Mo) nitrogenase, vanadium (V) nitrogenase, and iron-only (Fe ...
The lighter isotope of nitrogen, 14 N, is preferred during denitrification, leaving the heavier nitrogen isotope, 15 N, in the residual matter. This selectivity leads to the enrichment of 14 N in the biomass compared to 15 N. [ 27 ] Moreover, the relative abundance of 14 N can be analyzed to distinguish denitrification apart from other ...
Diazotroph fertilizer is a kind of biofertilizer that can use nitrogen-fixing microorganisms to convert molecular nitrogen (N 2) into ammonia (which is the formation of nitrogen available for the crops to use). These nitrogen nutrients then can be used in the process of protein synthesis for the plants.
Heterocysts or heterocytes are specialized nitrogen-fixing cells formed during nitrogen starvation by some filamentous cyanobacteria, such as Nostoc, Cylindrospermum, and Anabaena. [1] They fix nitrogen from dinitrogen (N 2) in the air using the enzyme nitrogenase, in order to provide the cells in the filament with nitrogen for biosynthesis. [2]
In the nitrogen cycle, atmospheric nitrogen gas is converted by plants into usable forms such as ammonia and nitrates through the process of nitrogen fixation. These compounds can be used by other organisms, and nitrogen is returned to the atmosphere through denitrification and other processes.