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The Corey–Seebach reaction, or Seebach Umpolung is a name reaction of organic chemistry that allows for acylation by converting aldehydes into lithiated 1,3-dithianes.The lithiated 1,3-dithianes serves as an acyl anion equivalent, undergoing alkylation with electrophiles. [1]
The Beilstein database is a database in the field of organic chemistry, in which compounds are uniquely identified by their Beilstein Registry Number.The database covers the scientific literature from 1771 to the present and contains experimentally validated information on millions of chemical reactions and substances from original scientific publications.
Wiley-Interscience, 3rd edition, 1999, ISBN 0-471-16019-9; Wiley-Interscience, 4th edition, 2007, ISBN 0-471-69754-0; Wiley-Interscience, 5th edition, 2014, ISBN 9781118057483; Description: A comprehensive reference for the usage of protecting groups in organic synthesis. Importance: A reference publication.
Aliquat 336 is used as a phase transfer catalyst, [2] including in the catalytic oxidation of cyclohexene to 1,6-hexanedioic acid. [3] This reaction is an example of green chemistry, as it is more environmentally friendly than the traditional method of oxidizing cyclohexanol or cyclohexanone with nitric acid or potassium permanganate, which produce hazardous wastes.
Elias James Corey (born July 12, 1928) is an American organic chemist.In 1990, he won the Nobel Prize in Chemistry "for his development of the theory and methodology of organic synthesis", [3] specifically retrosynthetic analysis.
Organocerium chemistry is the science of organometallic compounds that contain one or more chemical bond between carbon and cerium. These compounds comprise a subset of the organolanthanides . Most organocerium compounds feature Ce(III) but some Ce(IV) derivatives are known.