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In organic chemistry, an anti-Bredt molecule is a bridged molecule with a double bond at the bridgehead. Bredt's rule is the empirical observation that such molecules only form in large ring systems. For example, two of the following norbornene isomers violate Bredt's rule, and are too unstable to prepare: Bridgehead atoms violating Bredt's ...
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Edward I. Solomon (born 1946) is the Monroe E. Spaght Professor of Chemistry at Stanford University. He is an elected member of the United States National Academy of Sciences , [ 1 ] a Fellow of the American Association for the Advancement of Science , and a Fellow of the American Academy of Arts and Sciences .
Migratory aptitude is the relative ability of a migrating group to migrate in a rearrangement reaction. [1] Migratory aptitudes vary in different reactions, depending on multiple factors.
Organic chemistry is a subdiscipline within chemistry involving the scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms. [1]
The following outline is provided as an overview of and topical guide to organic chemistry: Organic chemistry is the scientific study of the structure, properties, composition, reactions, and preparation (by synthesis or by other means) of carbon-based compounds, hydrocarbons, and their derivatives.
Physical organic chemistry is the study of the relationship between structure and reactivity of organic molecules.More specifically, physical organic chemistry applies the experimental tools of physical chemistry to the study of the structure of organic molecules and provides a theoretical framework that interprets how structure influences both mechanisms and rates of organic reactions.
Isaac Newton's diagram of part of the Temple of Solomon, taken from Plate 1 of The Chronology of Ancient Kingdoms Amended (published London, 1728) Newton extensively studied and wrote about the Temple of Solomon , dedicating an entire chapter of The Chronology of Ancient Kingdoms Amended to his observations of the temple.