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Iron (II) hydroxide or ferrous hydroxide is an inorganic compound with the formula Fe(OH) 2. It is produced when iron (II) salts, from a compound such as iron(II) sulfate, are treated with hydroxide ions. Iron(II) hydroxide is a white solid, but even traces of oxygen impart a greenish tinge. The air-oxidised solid is sometimes known as "green ...
Lawrencite, (Fe,Ni)Cl 2, is the natural counterpart, and a typically (though rarely occurring) meteoritic mineral. [14] The natural form of the dihydrate is rokühnite - a very rare mineral. [ 15 ] Related, but more complex (in particular, basic or hydrated) minerals are hibbingite , droninoite and kuliginite .
Iron(III) oxide-hydroxide or ferric oxyhydroxide [2] is the chemical compound of iron, oxygen, and hydrogen with formula FeO(OH). The compound is often encountered as one of its hydrates, FeO(OH) ·n H 2 O [rust]. The monohydrate FeO(OH) · H 2 O is often referred to as iron(III) hydroxide Fe(OH) 3, [3] hydrated iron oxide, yellow iron oxide ...
For example, "ferrous sulfide" can refer to the 1:1 species (mineral name troilite) or a host of Fe-deficient derivatives . The mineral magnetite ("lode stone") is a mixed-valence compound with both Fe(II) and Fe(III), Fe 3 O 4.
Structure of [Co 2 (OH 2) 10] 4+ color code: red = O, white = H, blue = Co. In the binuclear ion [Co 2 (OH 2) 10] 4+ each bridging water molecule donates one pair of electrons to one cobalt ion and another pair to the other cobalt ion. The Co-O (bridging) bond lengths are 213 picometers, and the Co-O (terminal) bond lengths are 10 pm shorter.
2 [fe(h 2 o) 4 (oh) 2] + ⇌ [fe 2 (h 2 o) 8 (oh) 2] + 2 + 2 h 2 o The aquo ligands on iron(III) complexes are labile. This behavior is visualized by the color change brought about by reaction with thiocyanate to give a deep red thiocyanate complex .
The sulfate salt [Fe(bipy) 3]SO 4 is produced by combining ferrous sulfate with excess bipy in aqueous solution. This result illustrates the preference of Fe(II) for bipyridine vs water. Addition of cyanide to this solution precipitates solid Fe(bipy) 2 (CN) 2. [2]
The formation of Fe(III)-EDTA (FeY) − can be described as follows: FeSO 4 ∙7H 2 O + K 2 H 2 Y + 1/4 O 2 → K[FeY(H 2 O)]. H 2 O + KHSO 4 + 5.5 H 2 O (1) [8]. Iron chelate has also been used as a bait in the chemical control of slugs, snails and slaters in agriculture in Australia and New Zealand.